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 <front>
  <journal-meta>
   <journal-id journal-id-type="publisher-id">Herald of Technological University</journal-id>
   <journal-title-group>
    <journal-title xml:lang="en">Herald of Technological University</journal-title>
    <trans-title-group xml:lang="ru">
     <trans-title>ВЕСТНИК ТЕХНОЛОГИЧЕСКОГО УНИВЕРСИТЕТА</trans-title>
    </trans-title-group>
   </journal-title-group>
   <issn publication-format="print">3034-4689</issn>
  </journal-meta>
  <article-meta>
   <article-id pub-id-type="publisher-id">60126</article-id>
   <article-categories>
    <subj-group subj-group-type="toc-heading" xml:lang="ru">
     <subject>СТРУКТУРА ВЕЩЕСТВА И ТЕОРИЯ ХИМИЧЕСКИХ ПРОЦЕССОВ</subject>
    </subj-group>
    <subj-group subj-group-type="toc-heading" xml:lang="en">
     <subject></subject>
    </subj-group>
    <subj-group>
     <subject>СТРУКТУРА ВЕЩЕСТВА И ТЕОРИЯ ХИМИЧЕСКИХ ПРОЦЕССОВ</subject>
    </subj-group>
   </article-categories>
   <title-group>
    <article-title xml:lang="en">ДЕГРАДАЦИЯ ПЕРФТОРСУЛЬФОНИРОВАННЫХ МЕМБРАН: АЛЛИЛЬНЫЕ МАКРОРАДИКАЛЫ</article-title>
    <trans-title-group xml:lang="ru">
     <trans-title>ДЕГРАДАЦИЯ ПЕРФТОРСУЛЬФОНИРОВАННЫХ МЕМБРАН: АЛЛИЛЬНЫЕ МАКРОРАДИКАЛЫ</trans-title>
    </trans-title-group>
   </title-group>
   <contrib-group content-type="authors">
    <contrib contrib-type="author">
     <name-alternatives>
      <name xml:lang="ru">
       <surname>Кадиров</surname>
       <given-names>М К</given-names>
      </name>
      <name xml:lang="en">
       <surname>Кадиров</surname>
       <given-names>М К</given-names>
      </name>
     </name-alternatives>
     <email>kamaka59@gmail.com</email>
     <xref ref-type="aff" rid="aff-1"/>
    </contrib>
    <contrib contrib-type="author">
     <name-alternatives>
      <name xml:lang="ru">
       <surname>Валитов</surname>
       <given-names>М И</given-names>
      </name>
      <name xml:lang="en">
       <surname>Валитов</surname>
       <given-names>М И</given-names>
      </name>
     </name-alternatives>
     <email>vmurad_5@mail.ru</email>
     <xref ref-type="aff" rid="aff-2"/>
    </contrib>
    <contrib contrib-type="author">
     <name-alternatives>
      <name xml:lang="ru">
       <surname>Кадирова</surname>
       <given-names>Д М</given-names>
      </name>
      <name xml:lang="en">
       <surname>Кадирова</surname>
       <given-names>Д М</given-names>
      </name>
     </name-alternatives>
     <email>dine@inbox.ru</email>
     <xref ref-type="aff" rid="aff-3"/>
    </contrib>
   </contrib-group>
   <aff-alternatives id="aff-1">
    <aff>
     <institution xml:lang="ru">КНИТУ; ИОФХ им. А.Е. Арбузова КазНЦ РАН</institution>
     <country>ru</country>
    </aff>
    <aff>
     <institution xml:lang="en">КНИТУ; ИОФХ им. А.Е. Арбузова КазНЦ РАН</institution>
     <country>ru</country>
    </aff>
   </aff-alternatives>
   <aff-alternatives id="aff-2">
    <aff>
     <institution xml:lang="ru">ИОФХ им. А.Е. Арбузова КазНЦ РАН</institution>
     <country>ru</country>
    </aff>
    <aff>
     <institution xml:lang="en">ИОФХ им. А.Е. Арбузова КазНЦ РАН</institution>
     <country>ru</country>
    </aff>
   </aff-alternatives>
   <aff-alternatives id="aff-3">
    <aff>
     <institution xml:lang="ru">КНИТУ</institution>
     <country>ru</country>
    </aff>
    <aff>
     <institution xml:lang="en">КНИТУ</institution>
     <country>ru</country>
    </aff>
   </aff-alternatives>
   <pub-date publication-format="print" date-type="pub" iso-8601-date="2025-08-01T12:53:58+03:00">
    <day>01</day>
    <month>08</month>
    <year>2025</year>
   </pub-date>
   <pub-date publication-format="electronic" date-type="pub" iso-8601-date="2025-08-01T12:53:58+03:00">
    <day>01</day>
    <month>08</month>
    <year>2025</year>
   </pub-date>
   <volume>16</volume>
   <issue>3</issue>
   <fpage>11</fpage>
   <lpage>15</lpage>
   <history>
    <date date-type="received" iso-8601-date="2023-04-19T15:35:04+03:00">
     <day>19</day>
     <month>04</month>
     <year>2023</year>
    </date>
   </history>
   <self-uri xlink:href="https://vestniktu.ru/en/nauka/article/60126/view">https://vestniktu.ru/en/nauka/article/60126/view</self-uri>
   <abstract xml:lang="ru">
    <p>Генерированы аллильные радикалы в главной цепи у основания боковой цепи перфторированных мембран. Сателлитные линии их квартетных спектров ЭПР в системах мембрана/вода образуются благодаря диполь-дипольному взаимодействию аллильного радикала с матричными протонами молекул воды, образующих водородные связи с мостиковыми кислородами у основания боковой цепи и атомами фтора главной цепи и становятся достаточно малоподвижными. Из анализа спектров ЭПР получены структурно-морфологические параметры.</p>
   </abstract>
   <trans-abstract xml:lang="en">
    <p>Allyl radicals have been generated in the main chain at the base of the side chain of perfluorinated membranes. Satellite lines of the quartet EPR spectra of membrane systems/water are forming due to the dipole-dipole interaction of the allyl radical with matrix protons of water molecules forming hydrogen bonds with the bridging oxygen at the bottom of the side chain and fluorine atoms of the main chain and become quite inactive. Structural and morphological parameters have been obtained from the analysis of the EPR spectra. </p>
   </trans-abstract>
   <kwd-group xml:lang="ru">
    <kwd>перфторированные мембраны</kwd>
    <kwd>аллильные радикалы</kwd>
    <kwd>матричные протоны</kwd>
    <kwd>водородная связь</kwd>
    <kwd>диполь-дипольное взаимодействие</kwd>
    <kwd>спектры ЭПР</kwd>
    <kwd>сателлитные линии</kwd>
    <kwd>структурно-морфологические параметры</kwd>
    <kwd>perfluorinated membranes</kwd>
    <kwd>allyl radicals</kwd>
    <kwd>matrix protons</kwd>
    <kwd>hydrogen bonding</kwd>
    <kwd>dipole-dipole interaction</kwd>
    <kwd>EPR spectra</kwd>
    <kwd>satellite lines</kwd>
    <kwd>structural and morphological parameters</kwd>
   </kwd-group>
   <kwd-group xml:lang="en">
    <kwd>перфторированные мембраны</kwd>
    <kwd>аллильные радикалы</kwd>
    <kwd>матричные протоны</kwd>
    <kwd>водородная связь</kwd>
    <kwd>диполь-дипольное взаимодействие</kwd>
    <kwd>спектры ЭПР</kwd>
    <kwd>сателлитные линии</kwd>
    <kwd>структурно-морфологические параметры</kwd>
    <kwd>perfluorinated membranes</kwd>
    <kwd>allyl radicals</kwd>
    <kwd>matrix protons</kwd>
    <kwd>hydrogen bonding</kwd>
    <kwd>dipole-dipole interaction</kwd>
    <kwd>EPR spectra</kwd>
    <kwd>satellite lines</kwd>
    <kwd>structural and morphological parameters</kwd>
   </kwd-group>
  </article-meta>
 </front>
 <body>
  <p></p>
 </body>
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