Herald of Technological University Herald of Technological University ВЕСТНИК ТЕХНОЛОГИЧЕСКОГО УНИВЕРСИТЕТА 3034-4689 60211 СТРУКТУРА ВЕЩЕСТВА И ТЕОРИЯ ХИМИЧЕСКИХ ПРОЦЕССОВ СТРУКТУРА ВЕЩЕСТВА И ТЕОРИЯ ХИМИЧЕСКИХ ПРОЦЕССОВ REACTIONS OF OZONE WITH ALCOHOLS, KETONES, ETHERS AND HYDROXYBENZENES (PART 1) Slavcho Kirillov Rakovsky Slavcho Kirillov Rakovsky rakovsky@ic.bas.bg Metody Anachkov Metody Anachkov Zaikov G E Zaikov G E chembio@sky.chph.ras.ru Stoyanov O V Stoyanov O V Sofina S Yu Sofina S Yu Corresponding author ru Corresponding author ru Institute of Catalysis, Bulgarian Academy of Sciences ru Institute of Catalysis, Bulgarian Academy of Sciences ru N.M. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences ru N.M. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences ru Kazan National Research Technological University ru Kazan National Research Technological University ru Kazan National Research Technological University ru Kazan National Research Technological University ru 01 08 2025 01 08 2025 16 4 11 16 19 04 2023 https://vestniktu.ru/en/nauka/article/60211/view

В статье рассматривается разложение органических веществ путем озонирования различных классов кислородсодержащих органических соединений – спиртов, кетонов, эфиров и гидроксибензенов. Обсуждены механизмы реакций озона с этими соединениями в органических растворителях, представлены соответствующие схемы реакций и приведены соответствующие кинетические и некоторые термодинамические параметры. Выявлены зависимости кинетики и механизма реакций озонирования от структуры соединений, среды и условий проведения реакций. Указаны и обсуждены различные возможности применения озонолиза. Все эти реакции имеют практическое значение для защиты окружающей среды.

The paper is focused on degradation of organics by ozonation and it comprises various classes of oxygen-containing organic compounds – alcohols, ketones, ethers and hydroxybenzenes. The mechanisms of ozone reactions with these compounds in organic solvents are discussed in details, the reaction schemes and the corresponding kinetic and some thermodynamic parameters are given. The dependences of the kinetics and the mechanism of the ozonation reactions on the structure of the compounds, on the medium and on the reaction conditions are revealed. The various possible applications of ozonolysis are specified and discussed. All these reactions have practical importance for the protection of the environment.

ozonation alcohols ketones ethers hydroxybenzenes kinetics mechanisms озонирование спирты кетоны эфиры гидроксибензены кинетика механизмы ozonation alcohols ketones ethers hydroxybenzenes kinetics mechanisms озонирование спирты кетоны эфиры гидроксибензены кинетика механизмы

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