It was studied properties of electrionc structure S-, O-aniones generated from 6-methyl-2-thio,- 2-thioalcyl(aralcyl)uracil. Quite electroinc energy of S-anion more then O-anion on 55.9 kJ/mol. Quantumchemical culculation and kinetic research of reaction S N2 substituation halogen in halogencontaining proove high selectiviity S-anion O-anion whith obtained 6-methyl-2-thio,- 2-thioalcyl(aralcyl)uracil.
квантово-химический расчет, метод ab-initio, 6-метил-2-тио-, 2-тиоалкил(аралкил) урацил, S- и О- анион, реакционная способность, quantum-chemical calculation, the method of ab-initio, 6-methyl-2- thio, 2-[tioalkil] (aralkyl) uracil, S and about the anion, reactivity
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