REAKCII N-TRET-BUTIL-2-HLORAL'DIMINA S O,O-DIALKILDITIOFOSFORNYMI KISLOTAMI
Abstract and keywords
Abstract (English):
There are two reaction centers in N-tert-butyl-2-chloroaldimine – tricoordinated nitrogen atom and C-Cl bond. Reaction of aldimine with O,O-dialkyldithiophosphoric acids proceeds on both of reaction centers with the formation of the O,O-dialkyldithiophosphatoaldimmonium salts. Firstly a protonation of nitrogen atom and then the substitution of chlorine atom by dithiophosphato group takes place.

Keywords:
N-трет-бутил-2-хлоральдимин, О, О-диалкилдитиофосфорные кислоты, соли 2-дитиофосфатоальдиммония, реакционные центры, последовательность процессов, интермедиат, структура, спектры ЯМР 1Н, 31Р и 13С, N-tert-butyl-2-chloroaldimine, О, O-dialkyldithiophosphoric acids, 2-dithiophosphatoaldimmonium salts, reaction center, sequence of processes, 1Н, 31Р and 13С NMR spectra
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