The reaction between bis(2-chloroethyl)arylphsphonite and ethyl chloracetate was studied by chromatography-mass-spectrometry method with electron ionization . It was shown, that oxides of starting phosphonite and its isomer are present in the reaction mixture. The fragmentation under electron ionization of all mixture components has studied.
хромато-масс-спектрометрия, этиловые эфиры 4-хлорэтокси(арилфосфорил)уксусных кислот, электронная ионизация, chromatography-mass-spectrometry, 4-chloroethoxy(arylphosphoryl) acetic acids ethyl esters, electron ionization
1. Yashin, Yu.S. Hromatomass-spektrometricheskiy analiz efirov fosfornoy i fosfonovoy kislot s primeneniem fotoionizacii pri atmosfernom davlenii / Yu.S. Yashin, I.A. Revel'skiy, I.N. Tihonova // Mass-spektrometriya. - 2006. - №2. - S.107-112
2. Lebedev, A.T. Mass-spektrometricheskaya identifikaciya vysokotoksichnyh alkilftorfosfonatov / A.T. Lebedev, K.S. Lebedev, B.F. Myasoedov, I.V. Rybal'chenko, G.I. Sigeykin, V.N. Suvorkin // Mass-spektrometriya. - 2006. - №4. - S.277-283
3. Kabachnik, M.I. Fosfororganicheskie soedineniya. II. Prevraschenie tris(2-hloretil)fosfita v proizvodnye pyativalentnogo fosfora / M.I. Kabachnik, P.A. Rossiyskaya // Izv. AN SSSR. - 1946. - Vyp. 4. - S. 403-410.