Herald of Technological University Herald of Technological University ВЕСТНИК ТЕХНОЛОГИЧЕСКОГО УНИВЕРСИТЕТА 3034-4689 63634 ХИМИЯ, ТЕХНОЛОГИЯ И ИСПОЛЬЗОВАНИЕ ПОЛИМЕРОВ ХИМИЯ, ТЕХНОЛОГИЯ И ИСПОЛЬЗОВАНИЕ ПОЛИМЕРОВ CHARACTERIZATION OF A PEARLESCENT BIAXIALLY ORIENTED MULTILAYER POLYPROPYLENE FILM. PART 1 Arkis E Arkis E Cetinkaya H Cetinkaya H Ulucan U Ulucan U Aytac A Aytac A Balci B Balci B Colak F Colak F Topagac Germen E Topagac Germen E Kutluay G Kutluay G Dilhan B Can Dilhan B Can Balkose D Balkose D Zaikov G Zaikov G Abzaldinov Kh Abzaldinov Kh ov_stoyanov@mail.ru Технологический Институт Измира, кафедра химической технологии, Измир, Турция ru Technological Institute of Izmir, the department of the chemical technology, Izmir, Turkey ru Технологический Институт Измира, кафедра химической технологии, Измир, Турция ru Technological Institute of Izmir, the department of the chemical technology, Izmir, Turkey ru Технологический Институт Измира, кафедра химической технологии, Измир, Турция ru Technological Institute of Izmir, the department of the chemical technology, Izmir, Turkey ru Технологический Институт Измира, кафедра химической технологии, Измир, Турция ru Technological Institute of Izmir, the department of the chemical technology, Izmir, Turkey ru Технологический Институт Измира, кафедра химической технологии, Измир, Турция ru Technological Institute of Izmir, the department of the chemical technology, Izmir, Turkey ru Технологический Институт Измира, кафедра химической технологии, Измир, Турция ru Technological Institute of Izmir, the department of the chemical technology, Izmir, Turkey ru Технологический Институт Измира, кафедра химической технологии, Измир, Турция ru Technological Institute of Izmir, the department of the chemical technology, Izmir, Turkey ru Технологический Институт Измира, кафедра химической технологии, Измир, Турция ru Technological Institute of Izmir, the department of the chemical technology, Izmir, Turkey ru Технологический Институт Измира, кафедра химической технологии, Измир, Турция ru Technological Institute of Izmir, the department of the chemical technology, Izmir, Turkey ru Технологический Институт Измира, кафедра химической технологии, Измир, Турция ru Technological Institute of Izmir, the department of the chemical technology, Izmir, Turkey ru Казанский национальный исследовательский технологический университет, Россия ru KNRTU ru Казанский национальный исследовательский технологический университет, Россия ru KNRTU ru 01 08 2025 01 08 2025 17 14 255 259 20 04 2023 https://vestniktu.ru/en/nauka/article/63634/view

В настоящей работе определены морфология, состав и свойства промышленной перламутровой, многослойной пленки БОПП. Исследована полипропиленовая биаксиально-ориентированная пленка, что было показано методом ИК-спектроскопии и рентгеноструктурным анализом. Методом ИК-спектроскопии обнаружены карбонат-ионы, анализ данных EDX указывает на присутствие Ca, рентгеноструктурный анализ показал наличие кальцита. Пленка толщиной 30 мкм состоит из основного слоя, наполненного кальцитом, а также ненаполненных верхнего и нижнего слоев толщиной 4 мкм, содержащих различные полимеры. В основном слое пленки обнаружены длинные воздушные полости с соотношениями сторон 23:19 в, соответственно, продольном и поперечном направлениях, придающие пленке перламутровый оттенок. Пленки имели очень гладкую поверхность с шероховатостью в диапазоне от 3,052 нм до 11,261 нм, что показано методом АСМ. Температура плавления пленки - 163,6 oС, степень кристалличности - 51%, размеры полимерных кристаллов - 6,3 нм при нагревании со скоростью 10 °С/мин.

The morphology, composition and properties of a commercial pearlescent and multilayer BOPP film were determined in the present study. The film was polypropylene and it was biaxially oriented as shown by FTIR spectroscopy and X-ray diffraction. FTIR spectroscopy indicated carbonate ions, EDX analysis indicated the presence of Ca element, X-ray diffraction showed the presence of calcite. The 30 µm film consisted of a core layer filled with calcite and 4 µm thick upper and lower layers without any filler and from different polymers. There were long air cavities in the core layer with aspect ratios of 23 and 19 in machine and transverse directions making the film pearlescent. The surfaces of the film were very smooth and had surface roughness in the range of 3.052 nm and 11.261 nm as determined by AFM. The film melted at 163.6 oC, had 51 % crystallinity and had 6.3 nm polymer crystals when heated at 10 oC/min rate.

pearlescent film BOPP x-ray diffraction SEM AFM перламутровая пленка БОПП рентгеноструктурный анализ СЭМ АСМ pearlescent film BOPP x-ray diffraction SEM AFM перламутровая пленка БОПП рентгеноструктурный анализ СЭМ АСМ

Nie H.Y, Walzak M. J., McIntyre N. S., Atomic force Microscope Study of Biaxially Oriented Films, Journal of Materials Engineering and Performance,2009, 13 (4) 4511-460. Nie H.Y, Walzak M. J., McIntyre N. S., Atomic force Microscope Study of Biaxially Oriented Films, Journal of Materials Engineering and Performance,2009, 13 (4) 4511-460. Introduction of BOPP Film http://decrobopp.wordpress.com (2013). Introduction of BOPP Film http://decrobopp.wordpress.com (2013). Longo C., Savaris M., Zeni M., Brandalise R. N., Grisa A.M.C., Degradation Study of Polypropylene and Bioriented Polyproylene in the Environment. Materials Research, 2011, 14 (4) 442-48. Longo C., Savaris M., Zeni M., Brandalise R. N., Grisa A.M.C., Degradation Study of Polypropylene and Bioriented Polyproylene in the Environment. Materials Research, 2011, 14 (4) 442-48. Raukula J. I., A New Technology to Manufacture Polypropylene Foam Sheet and Biaxially Oriented Foam Film; Thesis, Technical Research Centre of Finland (1998). Raukula J. I., A New Technology to Manufacture Polypropylene Foam Sheet and Biaxially Oriented Foam Film; Thesis, Technical Research Centre of Finland (1998). Ulku S., Balkose D., Arkis E.,Sipahioglu, M., A study of chemical and physical changes during biaxially oriented polypropylene film production, Journal of Polymer Engineering, 2003, 23, 437-456, Ulku S., Balkose D., Arkis E.,Sipahioglu, M., A study of chemical and physical changes during biaxially oriented polypropylene film production, Journal of Polymer Engineering, 2003, 23, 437-456, Kalapat N. and Amornsakchai T., Surface modification of biaxially oriented poly-propylene (BOPP) film using acrylic acid-corona treatment: Part I. Properties and characterization of treated films, Surface and Coating Technology,2012, 207, 594-601. Kalapat N. and Amornsakchai T., Surface modification of biaxially oriented poly-propylene (BOPP) film using acrylic acid-corona treatment: Part I. Properties and characterization of treated films, Surface and Coating Technology,2012, 207, 594-601. Nago, S. and Mizutani, Y., Microporous Polypropylene Sheets Containing CaCO3 Filler: Effects of Stretching Ratio and Removing CaCO3 Filler Journal of Applied Polymer Science, 1998, 68, 1543-1553 Nago, S. and Mizutani, Y., Microporous Polypropylene Sheets Containing CaCO3 Filler: Effects of Stretching Ratio and Removing CaCO3 Filler Journal of Applied Polymer Science, 1998, 68, 1543-1553 Opaque polymeric films and processes making the sameUS patent 6183856B1,2001 Opaque polymeric films and processes making the sameUS patent 6183856B1,2001 Koleske JV, Paint and Coating Testing Manual, 14th ed., the Gardner-Sward Ed., Philadelphia, PA: ASTM, 1995. Koleske JV, Paint and Coating Testing Manual, 14th ed., the Gardner-Sward Ed., Philadelphia, PA: ASTM, 1995. http://www.plastemart.com/upload/literature/246_art_bopp_in_foodpack.asp (2014). http://www.plastemart.com/upload/literature/246_art_bopp_in_foodpack.asp (2014). Biswas J., Kim H., Lee B.H., Choe S., Air-hole properties of calcite-filled polypropylene copolymer films. 2008 Journal of Applied Polymer Science, 109, 1420-1430 Biswas J., Kim H., Lee B.H., Choe S., Air-hole properties of calcite-filled polypropylene copolymer films. 2008 Journal of Applied Polymer Science, 109, 1420-1430 Nie H.-Y, Walzak M.J., McIntyre N.S. Atomic Force Microscopy Study of Biaxially-Oriented Polypropylene Films JMEPEG, 2004, 13,451-460 Nie H.-Y, Walzak M.J., McIntyre N.S. Atomic Force Microscopy Study of Biaxially-Oriented Polypropylene Films JMEPEG, 2004, 13,451-460 Nie H.-Y. , Walzak M.J., McIntyre N.S. Draw-ratio-dependent morphology of biaxially oriented polypropylene films as determined by atomic force microscopy Polymer, 2000, 41, 2213-2218 Nie H.-Y. , Walzak M.J., McIntyre N.S. Draw-ratio-dependent morphology of biaxially oriented polypropylene films as determined by atomic force microscopy Polymer, 2000, 41, 2213-2218 Izer A., Kahyaoglu T. N., Balkose D., Valcium Soap Lubricants, Scince Journal of Volgograd State University, 10, 1, 16-25 Izer A., Kahyaoglu T. N., Balkose D., Valcium Soap Lubricants, Scince Journal of Volgograd State University, 10, 1, 16-25 Chen J., Xiang L, Controllable synthesis of calcium carbonate polymorphs at different temperatures, Powder Technology, 2009, 189, 64 - 69 Chen J., Xiang L, Controllable synthesis of calcium carbonate polymorphs at different temperatures, Powder Technology, 2009, 189, 64 - 69 Diez, F. J., Alvarino, C., Lopez, J., Ramirez, C. Abad, M. J., Cano, J., Garcia-Garabal, S. and Barral, L., “Influence of the Stretching in the Crystallinity of Biaxially Oriented Polypropylene (BOPP) Films,” Journal of Thermal Analysis and Calorimetry, 2005, 81, pp. 21-25. Diez, F. J., Alvarino, C., Lopez, J., Ramirez, C. Abad, M. J., Cano, J., Garcia-Garabal, S. and Barral, L., “Influence of the Stretching in the Crystallinity of Biaxially Oriented Polypropylene (BOPP) Films,” Journal of Thermal Analysis and Calorimetry, 2005, 81, pp. 21-25. Data from JCPDS Card Index File, Card 5-5868 Data from JCPDS Card Index File, Card 5-5868 Yang W., Li Z-M., Xie B.-H., Feng J-M., Shi W., Yang M-B. Stress-Induced Crystallization of Biaxially Oriented Polypropylene Journal of Applied Polymer Science, 2003, 89, 686-690 Yang W., Li Z-M., Xie B.-H., Feng J-M., Shi W., Yang M-B. Stress-Induced Crystallization of Biaxially Oriented Polypropylene Journal of Applied Polymer Science, 2003, 89, 686-690 Bu H.S., Cheng S.Z.D., Wunderlich B. Addendum to the thermal properties of polypropylene. Die Makromolekulare Chemie Rapid Communications 1988,89(2), 75-77 Bu H.S., Cheng S.Z.D., Wunderlich B. Addendum to the thermal properties of polypropylene. Die Makromolekulare Chemie Rapid Communications 1988,89(2), 75-77 Yamada K., Hikosaka M., Toda A., Yamazaki S., Tagashira K. Equilibrium melting temperature of isotactic polypropylene with high tacticity: 1. Determination by differential scanning calorimetry Macromolecules, 2003,36,4790-4801 Yamada K., Hikosaka M., Toda A., Yamazaki S., Tagashira K. Equilibrium melting temperature of isotactic polypropylene with high tacticity: 1. Determination by differential scanning calorimetry Macromolecules, 2003,36,4790-4801 http://en.wikipedia.org/wiki/Polypropylene http://en.wikipedia.org/wiki/Polypropylene http://www.surface-tension.de/solid-surface-energy.htm http://www.surface-tension.de/solid-surface-energy.htm