Herald of Technological University Herald of Technological University ВЕСТНИК ТЕХНОЛОГИЧЕСКОГО УНИВЕРСИТЕТА 3034-4689 59627 ХИМИЯ, ТЕХНОЛОГИЯ И ИСПОЛЬЗОВАНИЕ ПОЛИМЕРОВ ХИМИЯ, ТЕХНОЛОГИЯ И ИСПОЛЬЗОВАНИЕ ПОЛИМЕРОВ THE CONDUCTIVITY OF POLYMER COMPOSITES (REVIEW) Jimsher Aneli Jimsher Aneli Gennady Zaikov Gennady Zaikov Omar Mukbaniani Omar Mukbaniani Alfonso Jimenez Alfonso Jimenez Khaidar Abzaldinov Khaidar Abzaldinov ov_stoyanov@mail.ru Javakhishvili Tbilisi State University, Chemical Department ru Javakhishvili Tbilisi State University, Chemical Department ru N.M. Emanuel Institute of Biochemical Physics of Russian Academy of Sciences ru N.M. Emanuel Institute of Biochemical Physics of Russian Academy of Sciences ru Tbilisi-Center, Georgia ru Tbilisi-Center, Georgia ru Alicante University, Chemical Faculty, Alicante, Spain ru Alicante University, Chemical Faculty, Alicante, Spain ru Kazan National Research Technological University ru Kazan National Research Technological University ru 01 08 2025 01 08 2025 15 20 96 107 19 04 2023 https://vestniktu.ru/en/nauka/article/59627/view

Рассмотрена роль структурных особенностей электропроводящих полимерных композитов. В обзоре представлены различные концепции о природе проводимости, механизмы переноса заряда в гетерогенных структурах. Экспериментальные результаты, полученные различными учеными, лишь отчасти соответствуют существующим теоретическим моделям. Предполагается, что отсутствие различных физических и химических факторов, влияющих на процессы формирования электрического тока в полимерных композитах является одной из основных причин расхождений между теорией и экспериментальными результатами, среди которых значения скоростей меж-и внутрифазовых взаимодействий в композитах. В работе также рассматриваются свойства систем, содержащих проводящие наполнители.

The role of the structural peculiarities of electrical conducting polymer composites (ECPC) has been considered. Different conception on the nature of the conductivity, the mechanisms of charge transfer in heterogeneous structures are presented in this review. Experimental results obtained by different scientists only partially are in concordance with existing theoretical models. It is suggested that missing of various physical and chemical factors influencing on the processes of electrical current formation in polymer composites is one of main reasons of mentioned divergence between theory and experimental results among which the rate of the values of inter and intra phase interactions in composites may be considered as very important factor. The peculiarities of dependence of the conductivity of systems with binary conducting fillers are considered in this work too.

полимерный композит структура электропроводность содержание наполнителя электропроводящие полимеры межфазные взаимодействия polymer composite structure electro-conductivity filler content electrical conducting polymers interphase interactions полимерный композит структура электропроводность содержание наполнителя электропроводящие полимеры межфазные взаимодействия polymer composite structure electro-conductivity filler content electrical conducting polymers interphase interactions

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