Herald of Technological University Herald of Technological University ВЕСТНИК ТЕХНОЛОГИЧЕСКОГО УНИВЕРСИТЕТА 3034-4689 59692 ТЕХНОЛОГИЯ ЭЛЕКТРОХИМИЧЕСКИХ ПРОИЗВОДСТВ ТЕХНОЛОГИЯ ЭЛЕКТРОХИМИЧЕСКИХ ПРОИЗВОДСТВ The reinforcement mechanism of nanocomposites polyethylene/organoclay on suprasegmental level Kozlov G V Kozlov G V Dibirova K S Dibirova K S Magomedov G M Magomedov G M Bob A Howell Bob A Howell Zaikov G E Zaikov G E Stoyanov O V Stoyanov O V ov_stoyanov@mail.ru Abzaldinov K S Abzaldinov K S Dagestan State Pedagogical University ru Dagestan State Pedagogical University ru Dagestan State Pedagogical University ru Dagestan State Pedagogical University ru agestan State Pedagogical University ru agestan State Pedagogical University ru Central Michigan University, Mount Pleasant, MI, USA ru Central Michigan University, Mount Pleasant, MI, USA ru N.M. Emanuel Institute of Biochemical Physics of Russian Academy of Sciences ru N.M. Emanuel Institute of Biochemical Physics of Russian Academy of Sciences ru azan National Research Technological University ru azan National Research Technological University ru Kazan National Research Technological University ru Kazan National Research Technological University ru 01 08 2025 01 08 2025 15 21 55 57 19 04 2023 https://vestniktu.ru/en/nauka/article/59692/view

Предложен структурный механизм наполненных органоглиной полимерных нанокомпозитов на супрасегментном уровне. Согласно этого механизма модуль упругости нанокомпозитов определяется по размеру областей локальной упорядоченности (нанокластерам) по аналогии с натуральным нанокомпозитом (полимером). Образование плотноупакованных поверхностных областей в нанокомпозитах при введении нанонаполнителей является физической основой уменьшения размеров нанокластеров.

The structural mechanism of polymer nanocomposites filled with organoclay on suprasegmental level was offered. Within the frameworks of this mechanism nanocomposites elasticity modulus is defined by local order domains (nanoclusters) sizes similarly to natural nanocomposites (polymers). Densely-packed interfacial regions formation in nanocomposites at nanofiller introduction is the physical basis of nanoclusters size decreasing.

нанокомпозит полиэтилен органоглина модуль упругости нанокластеры межфазные области Nanocomposite polyethylene organoclay elasticity modulus nanoclusters interfacial regions нанокомпозит полиэтилен органоглина модуль упругости нанокластеры межфазные области Nanocomposite polyethylene organoclay elasticity modulus nanoclusters interfacial regions

Ahmed S., Jones F.R. J. Mater. Sci., 1990, v. 25, № 12, p. 4933-4942. Ahmed S., Jones F.R. J. Mater. Sci., 1990, v. 25, № 12, p. 4933-4942. Bobryshev A.N., Kozomazov V.N., Babin L.O., Solomatov V.I. Synergetics of Composite Materials. Lipetsk, NPO ORIUS, 1994, 154 p. Bobryshev A.N., Kozomazov V.N., Babin L.O., Solomatov V.I. Synergetics of Composite Materials. Lipetsk, NPO ORIUS, 1994, 154 p. Kozlov G.V., Yanovskii Yu.G., Zaikov G.E. Structure and Properties of Particulate-Filled Polymer Composites: the Fractal Analysis. New York, Nova Science Publishers, Inc., 2010, 282 p. Kozlov G.V., Yanovskii Yu.G., Zaikov G.E. Structure and Properties of Particulate-Filled Polymer Composites: the Fractal Analysis. New York, Nova Science Publishers, Inc., 2010, 282 p. Hotta S., Paul D.R. Polymer, 2004, v. 45, № 21, p. 7639-7654. Hotta S., Paul D.R. Polymer, 2004, v. 45, № 21, p. 7639-7654. Sheng N., Boyce M.C., Parks D.M., Rutledge G.C., Abes J.I., Cohen R.E. Polymer, 2004, v. 45, № 2, p. 487-506. Sheng N., Boyce M.C., Parks D.M., Rutledge G.C., Abes J.I., Cohen R.E. Polymer, 2004, v. 45, № 2, p. 487-506. Bashorov M.T., Kozlov G.V., Mikitaev A.K. Materialovedenie, 2009, № 9, p. 39-51. Bashorov M.T., Kozlov G.V., Mikitaev A.K. Materialovedenie, 2009, № 9, p. 39-51. Kozlov G.V., Novikov V.U. Uspekhi Fizicheskikh Nauk, 2001, v. 171, № 7, p. 717-764. Kozlov G.V., Novikov V.U. Uspekhi Fizicheskikh Nauk, 2001, v. 171, № 7, p. 717-764. Kozlov G.V., Zaikov G.E. Structure of the Polymer Amorphous State. Utretch, Boston, Brill Academic Publishers, 2004, 465 p. Kozlov G.V., Zaikov G.E. Structure of the Polymer Amorphous State. Utretch, Boston, Brill Academic Publishers, 2004, 465 p. Mikitaev A.K., Kozlov G.V., Zaikov G.E. Polymer Nanocomposites: Variety of Structural Forms and Applications. New York, Nova Science Publishers, Inc., 2008, 319 p. Mikitaev A.K., Kozlov G.V., Zaikov G.E. Polymer Nanocomposites: Variety of Structural Forms and Applications. New York, Nova Science Publishers, Inc., 2008, 319 p. Kozlov G.V., Mikitaev A.K. Polymers as Natural Nanocomposites: Unrealized Potential. Saarbrücken, Lambert Academic Publishing, 2010, 323 p. Kozlov G.V., Mikitaev A.K. Polymers as Natural Nanocomposites: Unrealized Potential. Saarbrücken, Lambert Academic Publishing, 2010, 323 p. Edwards D.C. J. Mater. Sci., 1990, v. 25, № 12, p. 4175-4185. Edwards D.C. J. Mater. Sci., 1990, v. 25, № 12, p. 4175-4185. Balankin A.S. Synergetics of Deformable Body. Moscow, Publishers of Ministry Defence SSSR, 1991, 404 p. Balankin A.S. Synergetics of Deformable Body. Moscow, Publishers of Ministry Defence SSSR, 1991, 404 p. Kozlov G.V., Sanditov D.S. Anharmonic Effects and Physical-Mechanical Properties of Polymers. Novosibirsk, Nauka, 1994, 261 p. Kozlov G.V., Sanditov D.S. Anharmonic Effects and Physical-Mechanical Properties of Polymers. Novosibirsk, Nauka, 1994, 261 p. Budtov V.P. Physical Chemistry of Polymer Solutions. Sankt-Peterburg, Khimiya, 1992, 384 p. Budtov V.P. Physical Chemistry of Polymer Solutions. Sankt-Peterburg, Khimiya, 1992, 384 p. Aharoni S.M. Macromolecules, 1985, v. 18, № 12, p. 2624-2630. Aharoni S.M. Macromolecules, 1985, v. 18, № 12, p. 2624-2630. Aharoni S.M. Macromolecules, 1983, v. 16, № 9, p. 1722-1728. Aharoni S.M. Macromolecules, 1983, v. 16, № 9, p. 1722-1728. Wu S. J. Polymer Sci.: Part B: Polymer Phys., 1989, v. 27, № 4, p. 723-741. Wu S. J. Polymer Sci.: Part B: Polymer Phys., 1989, v. 27, № 4, p. 723-741. Kozlov G.V. Recent Patents on Chemical Engineering, 2011, v. 4, № 1, p. 53-77. Kozlov G.V. Recent Patents on Chemical Engineering, 2011, v. 4, № 1, p. 53-77.