Herald of Technological University Herald of Technological University ВЕСТНИК ТЕХНОЛОГИЧЕСКОГО УНИВЕРСИТЕТА 3034-4689 62895 ХИМИЯ, ТЕХНОЛОГИЯ И ИСПОЛЬЗОВАНИЕ ПОЛИМЕРОВ ХИМИЯ, ТЕХНОЛОГИЯ И ИСПОЛЬЗОВАНИЕ ПОЛИМЕРОВ CARBON BLACK MIGRATION AND LOCALIZATION IN THE HETEROGENOUS POLYMERIC BLENDS Zaikin A E Zaikin A E azaikin@mail.ru Bobrov G B Bobrov G B dycnm@mail.ru Department of Plastic Technologies, Kazan National Research Technological University ru Department of Plastic Technologies, Kazan National Research Technological University ru Department of Plastic Technologies, Kazan National Research Technological University ru Department of Plastic Technologies, Kazan National Research Technological University ru 01 08 2025 01 08 2025 17 7 136 144 20 04 2023 https://vestniktu.ru/en/nauka/article/62895/view

Изучены причины и условия накопления технического углерода на поверхности раздела фаз в гетерогенных смесях полимеров, освещены некоторые термодинамические и кинетические данные этого процесса. Миграция частиц технического углерода из фазы на поверхность раздела фаз обуславливается термодинамикой их смачивания фазой полимера и подвергается влиянию термодинамических и кинетических особенностей адсорбции макромолекул на твердой поверхности.

The causes and conditions necessary for carbon black accumulation at the interface in heterogeneous binary polymer blends have been studied, and some thermodynamic and kinetic facets of the phenomenon have been elucidated. The migration of carbon black particles from a phase to the interface has been to be governed by the thermodynamics of wetting the particles by polymer phases and is affected by the thermodynamic and kinetic peculiarities of macromolecule adsorption on a solid surface. .

гетерогенная смесь полимеров технический углерод миграция локализация поверхность адсорбция heterogeneous polymer blends carbon black migration localization interface adsorption гетерогенная смесь полимеров технический углерод миграция локализация поверхность адсорбция heterogeneous polymer blends carbon black migration localization interface adsorption

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