THE EFFECT OF A COMPLEX CARBON-MINERAL COMPOSITE ON THE ADHESIVE STRENGTH TO STEEL OF COMPOSITIONS WITH MALEINIZED POLYETHYLENE AND ETHYLENE-VINYL ACETATE COPOLYMER

Sergey Tutov; V. V. Bushkov; Konstantin Vernigorov; V. I. Mashukov; S N Rusanova; S. A. Efremov; M. V. Sayfutdinova; S S Ahtyamova; I A Zagidullina; Yurij Kazakov; O V Stoyanov

doi:10.55421/3034-4689_2026_29_8_64

THE EFFECT OF A COMPLEX CARBON-MINERAL COMPOSITE ON THE ADHESIVE STRENGTH TO STEEL OF COMPOSITIONS WITH MALEINIZED POLYETHYLENE AND ETHYLENE-VINYL ACETATE COPOLYMER

Published in Herald of Technological University · Volume 29, Issue 8, 2026 · Pages 64–68 · Rubric: 2. Chemical Technology

DOI: https://doi.org/10.55421/3034-4689_2026_29_8_64 · EDN: CFHHFF

Received: 06.06.2026 Accepted: 21.07.2026 Published: 28.08.2026

Authors

Sergey Tutov

V. V. Bushkov

Konstantin Vernigorov

V. I. Mashukov

et al.

S N Rusanova

S. A. Efremov

M. V. Sayfutdinova

S S Ahtyamova

I A Zagidullina

Yurij Kazakov

O V Stoyanov

Sergey Tutov

OOO "Sibur" Russian Federation

V. V. Bushkov

OOO «SIBUR» Russian Federation

Konstantin Vernigorov

OOO «Sibur PoliLab» Russian Federation

V. I. Mashukov

OOO "Sibur PoliLab" Russian Federation · Москва

S N Rusanova

KNITU; KNRTU

S. A. Efremov

Al-Farabi Kazakh National University Almaty

Nacional'naya inzhenernaya akademiya Respubliki Kazahstan Russian Federation

M. V. Sayfutdinova

Kazan State Technological University Russian Federation · Kazan’

S S Ahtyamova

KNITU; Kazan national research technological University

I A Zagidullina

KNITU

Yurij Kazakov

Academic degree: doctor of technical sciences

Science rang: docent

Kazan National Research Technological University Kazan

O V Stoyanov

Kazanskiy nacional'nyy issledovatel'skiy tehnologicheskiy universitet

ABSTRACT

Currently, maleinated polyolefins are widely used as adhesive additives to improve the compatibility of polymers and fillers, in mixtures of polar and nonpolar polymers, to increase adhesion to various substrates. Scientific research is aimed at expanding the range of polyolefins modified with maleic anhydride, improving the technological processes of grafting anhydride to macromolecules, and developing composite materials based on grafted copolymers of polyolefins and anhydrides. To solve the latter problem, new, previously unused fillers and other additives are used to achieve the required performance. The effect of a carbon-mineral filler (CMF) on the adhesive characteristics of a mixture of linear low-pressure polyethylene and maleinized polyethylene, as well as an ethylene copolymer with vinyl acetate (EVA) modified with maleic anhydride, was studied. It was found that the introduction of CMF into the studied polymers leads to an extreme increase in the adhesive strength to steel by 26 % (for a mixture of polyethylene) and 1.5 times (for maleated carbon fiber). The use of the organosilicon modifier 3-glycidoxypropyltrimethoxysilane for maleinized savylene increases the strength of adhesive contact with steel by 51 %. The combined introduction of glycidoxysilane and CMF into maleinized EVA allows for an increase in adhesion by 8 % compared to using only 10 % by weight of glycidoxysilane. Considering that carbon-mineral filler is a waste product of coal shale mining and, accordingly, has a low cost, its use for the development of adhesive materials for corrosion protection of main steel pipelines seems promising. Its use will improve the operational characteristics of adhesive compositions, as well as solve the problems of reducing the environmental burden on the environment through the use of waste from the mining industry.

KEYWORDS

GRAFTED COPOLYMERS, MALEINIZED POLYOLEFINS, FILLER, MODIFIERS, ADHESIVE STRENGTH

Funding

Issledovanie vypolneno v ramkah Gosudarstvennogo zadaniya №075-00021-26-00 ot 12.01.2026 (FZSG-2026-0003).

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Tutov S. V., Bushkov V. V., Vernigorov K. B., Mashukov V. I., , Efremov S. A., Sayfutdinova M. V., , , Kazakov Y. M., THE EFFECT OF A COMPLEX CARBON-MINERAL COMPOSITE ON THE ADHESIVE STRENGTH TO STEEL OF COMPOSITIONS WITH MALEINIZED POLYETHYLENE AND ETHYLENE-VINYL ACETATE COPOLYMER // Herald of Technological University. 2026. no. 8. pp. 64-68. DOI: https://doi.org/10.55421/3034-4689_2026_29_8_64. EDN: CFHHFF. (Date of access 21.09.2026).

MLA

Sergey Tutov, Bushkov V. V., Vernigorov K. B., Mashukov V. I., , Efremov S. A., Sayfutdinova M. V., , , Kazakov Y. M., . "THE EFFECT OF A COMPLEX CARBON-MINERAL COMPOSITE ON THE ADHESIVE STRENGTH TO STEEL OF COMPOSITIONS WITH MALEINIZED POLYETHYLENE AND ETHYLENE-VINYL ACETATE COPOLYMER." Herald of Technological University 29.8 (2026): 64-68. DOI: https://doi.org/10.55421/3034-4689_2026_29_8_64. EDN: CFHHFF.

APA

Tutov S. V., Bushkov V. V., Vernigorov K. B., Mashukov V. I., , Efremov S. A., Sayfutdinova M. V., , , Kazakov Y. M., (2026). THE EFFECT OF A COMPLEX CARBON-MINERAL COMPOSITE ON THE ADHESIVE STRENGTH TO STEEL OF COMPOSITIONS WITH MALEINIZED POLYETHYLENE AND ETHYLENE-VINYL ACETATE COPOLYMER. Herald of Technological University, 29(8), 64-68. https://doi.org/10.55421/3034-4689_2026_29_8_64 EDN: CFHHFF.

Chicago

Sergey Tutov, Bushkov V. V., Vernigorov K. B., Mashukov V. I., , Efremov S. A., Sayfutdinova M. V., , , Kazakov Y. M., . "THE EFFECT OF A COMPLEX CARBON-MINERAL COMPOSITE ON THE ADHESIVE STRENGTH TO STEEL OF COMPOSITIONS WITH MALEINIZED POLYETHYLENE AND ETHYLENE-VINYL ACETATE COPOLYMER." Herald of Technological University 29, no. 8 (2026): 64-68. https://doi.org/10.55421/3034-4689_2026_29_8_64. EDN: CFHHFF.

WIKI

{{cite journal | author = Tutov S. V., Bushkov V. V., Vernigorov K. B., Mashukov V. I., , Efremov S. A., Sayfutdinova M. V., , , Kazakov Y. M., | title = THE EFFECT OF A COMPLEX CARBON-MINERAL COMPOSITE ON THE ADHESIVE STRENGTH TO STEEL OF COMPOSITIONS WITH MALEINIZED POLYETHYLENE AND ETHYLENE-VINYL ACETATE COPOLYMER | journal = Herald of Technological University | year = 2026 | volume = 29 | issue = 8 | pages = 64-68 | doi = 10.55421/3034-4689_2026_29_8_64 }} EDN: CFHHFF

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THE EFFECT OF A COMPLEX CARBON-MINERAL COMPOSITE ON THE ADHESIVE STRENGTH TO STEEL OF COMPOSITIONS WITH MALEINIZED POLYETHYLENE AND ETHYLENE-VINYL ACETATE COPOLYMER

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