Были синтезированы ароматические полиимиды и полиамиды на основе 4,4'-диаминотрифенилметана. Были изучены их термические, реологические свойства и растворимость в различных органических растворителях. Показано, что растворимость полученных полимеров связана со свободным внутренним вращением трифенилметанола и эффектом объемного фенильного заместителя в диаминодифенилметане.
aromatic polyamides, aromatic polyimides, 4,4’-diaminothreephenylmethane, synthesis, properties, ароматические полиамиды, ароматические полиамиды, 4,4'-диаминотрифенилметан, синтез, свойства
1. Weil Н., Sapper Е., Kramer Е., Kloter К., Selberg Н. Uber Diaminotriphenylmethan und Ahnliches. // Ber. 1928. Bd.61. №6. S.1294-1307.
2. Cherry N.A., Borukaev T.A., Telescopical M.A., O.V. Vasilieva, mikitaev A.K. Synthesis of aromatic polyazomethines based on 4,4’ - diaminodiphenylmethane. // J. High-molecular connection, Series A. 1993. Volume 35. №9. P 1420.
3. LiKhatchev D. Yu., Tlenkopachev M. A., Vilar R., Salcedo R., Ogawa T.,Borukaev T., Vishnevaya N. A., Bekanov M. Ch., Mikitaev A. K.//International Symposium on Polymers “POLYMEX-93”, Cancun. 1993. P. 176.
4. Kardash I.E., Likhachev DO, Krotovich MB, N.V. Kozlov, I. Zhuravlev, Bogachev US, the Righteous A.N. IR - and NMR-spectroscopic investigation of substituted N-phenylmaleimide as model compounds of aromatic polyimides.// J. High-molecular connection, Series A. 1987. Volume 29. №7. P 1369.
5. Vasilenko N.A., Ahmetova E.I., Sviridov E.B., Berendyaev VI, Rogozhkin DU, Alkaeu OF, Koshelev KK, Izyumnikova A.L., Cats BV Soluble polyimides based 4,4’ - diaminodiphenylmethane. Synthesis, molecular-mass characteristics, properties of solutions. // Journal “High-molecular compounds”, Series A. 1991. Volume 33. №7. P 1560.
6. Cvetkov, V. N., Stennikova, I. N., Lavrenko P.N. Konformation und Gleichgewichts-Flexibilität von Poly(tetraphenylmethan-terephthalamid)-Molekülen in Lösung. Acta Polymerica - Weinheim: 1980. Vol. 31. №7. p. 434-438.
7. Likhachev DO, Arzhakov MS, Chains, S.N., Sinevich E.A., Teeth Y.A, Kardash I.E., the Righteous A.N. The effect of the chemical structure on properties of aromatic polyimides, obtained by the method of chemical cyclization. // J.High-molecular connection, Series B. 1985. 27. Number 10. P 728.
8. Kardash I.E., Likhachev DO, Nikitin N.V., Ardashnikov YA, N.V. Kozlov, the Righteous A.N. Plasticizing effect of the solvent in the process of solid-phase thermal cyclization of aromatic polyamidation in the polyimides.// J. High-molecular the connection. Series A. 1985. 27. №8. P 1751.
9. Clair T. L. st., Clair A. K., st., Smith E. N. Structure- Solubility Re Lationships in Polymers. Eds. Harris F. W., Academic Press. 1997. P. 199.
10. Sprague J.T., Tai J.C., Yuh Y., Allinger N.L., Stewart J.P. The MMP2 calculational method. // J. Comput. Chem. 1987; p. 581-603.
11. Dewar M.J.S., Zoebisch E.G., Healy E.F., Stewart J.P. The development and use of quantum mechanical molecular models a new general purpose quantum mechanical molecular model. // J. Amer. Chem. Soc. 1985. Vol.107. р. 3902-3909.
12. Bessonov M. I., Kotov M. M., Kudryavtsev V. V., Latus L. A. Polyimides - Thermally Stable Polymers. USSR. Plenum. USA. 1987.
13. T.M. Birshtein, Goryunov A. I. Theoretical analysis of flexibility polyimides and polyamidation.//high-Molecular the connection. Series A. 1979. Volume 21. № 9. P 1997.
14. Vinogradova S.V., Profitable AS, Vorob'ev E, N.A. Churochkina, Codina LI, Spirina T.N., The Korshak V.V. Investigation of chemical cyclization of polyamidation in solution.//high-Molecular the connection. Series A. 1974. Volume 16. №3. P 510.
15. Clair T. I., Wllson D., Stenzenbergen H. D. St. Polyamides. Blac kie Son. 1990. P.297.
16. Du Pont High Perfomance Films: Summury of Properties 1993. 231302 A. USA.
17. Likhachev DO, Chains, S.N., Teeth Y.A, Nurmukhametov R.N., Kardash I.E. the Influence of defects chemical structure on the morphology of polyimide films. // high-Molecular the connection. Series A. 1991. Volume 33. № 9. P 20.