Raschet srednih topologicheskih parametrov polibutilakrilata ishodya iz kineticheskoy modeli processa ego sinteza – «zhivoy» radikal'noy polimerizacii v rezhime obratimoy peredachi cepey po mehanizmu «prisoedineniya-fragmentacii»

E V Samarin; D S. Kalinina; I I Nasyrov; R Y. Deberdeev; K A Tereschenko; N V Ulitin

UDC

541(64+127) : 547.538.141

RASCHET SREDNIH TOPOLOGICHESKIH PARAMETROV POLIBUTILAKRILATA ISHODYA IZ KINETICHESKOY MODELI PROCESSA EGO SINTEZA – «ZHIVOY» RADIKAL'NOY POLIMERIZACII V REZHIME OBRATIMOY PEREDACHI CEPEY PO MEHANIZMU «PRISOEDINENIYA-FRAGMENTACII» Raschet srednih topologicheskih parametrov polibutilakrilata ishodya iz kineticheskoy modeli processa ego sinteza – «zhivoy» radikal'noy polimerizacii v rezhime obratimoy peredachi cepey po mehanizmu «prisoedineniya-fragmentacii»

АА Аа

Published in Herald of Technological University · Pages 127–128 · Rubric: HIMIYa, TEHNOLOGIYa I ISPOL'ZOVANIE POLIMEROV

Received: 19.04.2023 Accepted: 01.08.2025 Published: 01.08.2025 Language of publication: RUS

Authors

E V Samarin

D S. Kalinina

I I Nasyrov

R Y. Deberdeev

K A Tereschenko

N V Ulitin

E V Samarin

KNITU

D S. Kalinina

KNITU

I I Nasyrov

KNITU

R Y. Deberdeev

KNITU

K A Tereschenko

KNITU

N V Ulitin

KNITU

ABSTRACT

The dependences of average topological parameters of polybutyl acrylate synthesized by the method of “living” radical polymerization in mode of reversible chain transfer by “addition-fragmentation” mechanism, on temperature of polymerization, initial concentrations of the monomer, the reversible chain transfer agent, the initiator (2,2 ’-azobisisobutyronitrile) have been defined. A number of computing experiments for the purpose to determine influence of operating factors on average topological parameters of polybutyl acrylate has been carried out.

KEYWORDS

численный эксперимент, обратимая передача цепи, полибутилакрилат, управляющий фактор, computing experiment, operating factor, polybutyl acrylate, reversible chain transfer

1. Ulitin N.V. Kineticheskaya model' processa radikal'noy polimerizacii butilakrilata v prisutstvii tritiokarbonatov / N.V. Ulitin, D.Sh. Kalinina, V.A. Sidel'nikova, T.R. Deberdeev // Vestnik Kazanskogo tehnologicheskogo universiteta. 2012. № 21. S. 67-70.

2. Ulitin N.V. Izuchenie vliyaniya upravlyayuschih faktorov na molekulyarno-massovye harakteristiki polistirola, poluchaemogo psevdozhivoy radikal'noy polimerizaciey / N.V. Ulitin, A.V. Oparkin, R.R. Nabiev // Vestnik Kazanskogo tehnologicheskogo universiteta. 2012. № 22. S. 80-81.

3. Zetterlund P.B. RAFT polymerization under microwave irradiation: Toward mechanistic understanding / P.B Zetterlund, S. Perrier // Macromolecules. 2011. V. 44. № 6. R. 1340-1352.

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Head of the Publishing house

Raziya Romanova

romanova_rg@mail.ru

Deputy Editor-in-Chief

Aleksandr Dresvyannikov

a.dresvyannikov@mail.ru

Executive Secretary

Svetlana Goryunova

svetlanagoryunova@yandex.ru

Editor-in-Chief

Yurij Kazakov

office@kstu.ru

Deputy Editor-in-Chief

Oleg Mickailov

olegmkhlv@gmail.com

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, , , , , Raschet srednih topologicheskih parametrov polibutilakrilata ishodya iz kineticheskoy modeli processa ego sinteza – «zhivoy» radikal'noy polimerizacii v rezhime obratimoy peredachi cepey po mehanizmu «prisoedineniya-fragmentacii» // Herald of Technological University. 2025. no. 7. pp. 127-128. (Date of access 07.09.2026).

MLA

E V Samarin, , , , , . "Raschet srednih topologicheskih parametrov polibutilakrilata ishodya iz kineticheskoy modeli processa ego sinteza – «zhivoy» radikal'noy polimerizacii v rezhime obratimoy peredachi cepey po mehanizmu «prisoedineniya-fragmentacii»." Herald of Technological University 16.7 (2025): 127-128.

APA

, , , , , (2025). Raschet srednih topologicheskih parametrov polibutilakrilata ishodya iz kineticheskoy modeli processa ego sinteza – «zhivoy» radikal'noy polimerizacii v rezhime obratimoy peredachi cepey po mehanizmu «prisoedineniya-fragmentacii». Herald of Technological University, 16(7), 127-128.

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{{cite journal | author = , , , , , | title = Raschet srednih topologicheskih parametrov polibutilakrilata ishodya iz kineticheskoy modeli processa ego sinteza – «zhivoy» radikal'noy polimerizacii v rezhime obratimoy peredachi cepey po mehanizmu «prisoedineniya-fragmentacii» | journal = Herald of Technological University | year = 2025 | volume = 16 | issue = 7 | pages = 127-128 }}

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