Oxygen impurities influence on texture and morphology of rhenium deposits surface in molten CsCl-Cs 2ReCl 6 was investigated. It was stated that oxygen influence was intensified in row: O/Re mol.. = 0,5 in argon atmosphere à O/Re mol. = 0 in air atmosphere à O/Re mol. = 1 in argon atmosphere à O/Re mol. = 1 in air atmosphere. Texture changes in row: (powder) à (compact layer without texture) à (10 0) à (11 0) à (10 L) with temperature increasing w ere observed. Grow texture (0001) wasn’t obtained in experiments. Oxygen impurities in rhenium deposits were found. Spherical forms on rhenium deposits surface produced from oxygen containing melts were observed. Their size and number increased with oxygen concentration and cathodic current density growing and decreasing of temperature.
лектроосаждение рения, влияние кислорода, изменение текстуры, rhenium electroplating, oxygen influence, texture change
1. Borisova L.V., Ermakov A.N. Analiticheskaya himiya reniya. - M: Nauka, 1974. - 319 s.
2. Druce I. Reniy. - M.: Izdatel'stvo inostrannoy literatury, 1951. - 116s.
3. Ryashenceva M.A., Minachev H.M. Reniy i ego soedineniya v geterogennom katalize. - M.: Nauka, 1983. - 249 s.
4. Palant A.A., Troshkina I.D., Chekmarev A.M. Metallurgiya reniya. - M.: Nauka, 2007. - 299 s.
5. Colton R. The chemistry of Rhenium and Technetium. - London - New York - Sydney: Interscience Publishers, 1965
6. Tribalat S. Rhenium et Technetium. - Paris: Gauthier-villars, 1957
7. Tribalat S. Rhenium. - Amsterdam-New York: Elsevier Publishing Co., 1962. - p. 191
8. Samsonov G.V., Epik A.P. Tugoplavkie pokrytiya. M.: Metallurgiya, 1973. - 400s.
9. Gazotermicheskie pokrytiya iz poroshkovyh materialov/ Yu.S.Borisov, Yu.A.Harlamov, S.L.Sidorenko, E.N.Ardatovskaya; - Kiev: Naukova Dumka. 1987. - 544 s.
10. Movchan B.A., Malashenko I.S. Zharostoykie pokrytiya, osazhdaemy v vakuume.- Kiev: Naukova dumka, 1983. - 232s.
11. Kostrzhickiy A.I., Lebedinskiy O.V. Mnogokomponentnye vakuumnye pokrytiya. - M.: Mashinostroenie, 1987. - 208 s.,
12. Kristallizaciya tugoplavkih metallov iz gazovoy fazy/ V.E. Ivanov, E.P. Nechiporenko, V.M. Krivoruchko, V.V.Sagalovich; - M.: Atomizdat, 1974.- 264s. 264s.
13. Osazhdenie plenok i pokrytiy razlozheniem metalloorganicheskih soedineniy/ B.G.Gribov, G.A. Domrachev, B.V. Zhuk, B.S. Kaverin, i dr.:AN SSSR IH.- M.: Nauka, 1981.-322 s.
14. Mel'nik P.I. Tehnologiya diffuzionnyh pokrytiy. - Kiev: TEHNIKA, 1978. - 151 s.
15. Filonenko B.A. Kompleksnye diffuzionnye pokrytiya. - M.: Mashinostroenie, 1981.- 136 s.
16. Yampol'skiy A.M. Elektroliticheskoe osazhdenie blagorodnyh i redkih metallov. - L.: Mashinostroenie, 1977.- 96 str.
17. Vas'ko A.T., Kovach S.K. Elektrohimiya tugoplavkih metallov. - Kiev: TEHNIKA, 1983.-160s.
18. Belen'kiy M.A., Ivanov F.A. Elektroosazhdenie metallicheskih pokrytiy. - M.:Metallurgiya,1985.-288 s.
19. Ginberg A.M. Gal'vanotehnika. Spravochnik. - M.: Metallurgiya, 1987.- 736 s.
20. Vinogradov-Zhabrov O.N., Molchanov A.M., Minchenko L.M. i dr. O vozmozhnosti primeneniya vysokotemperaturnogo gal'vanoplasticheskogo metoda dlya izgotovleniya izdeliy iz reniya i molibdena. //Cvetnaya metallurgiya.- 1998.- №11-12.- S.32-34.
21. A.S. 281993 SSSR, MKI 48 v 1/16. Elektrohimicheskiy sposob osazhdeniya reniya iz rasplavov./A.N.Baraboshkin, N.A.Saltykova, O.N.Vinogradov-Zhabrov, A.M.Molchanov.-Opubl.14.09.70, - BI№29.
22. A.S. 528357 SSSR, MKI S25D v 3/36. Rasplav dlya elektrohimicheskogo naneseniya renievyh pokrytiy./A.N.Baraboshkin, N.A.Saltykova, O.N.Vinogradov-Zhabrov, A.M.Molchanov.-Opubl.14.09.70, - BI№29.
23. A.S. 2467453 SSSR Sposob i rasplav dlya elektroosazhdeniya renievyh pokrytiy. / Vinogradov-Zhabrov O.N., Baraboshkin A.N., Molchanov A.M. i dr. - №670693, zayavl. 25.03.77 opubl.30.06.79g. - BI№24
24. Ermakov V.I., Neustroev V.I., Vinogradov-Zhabrov O.N. Poluchenie renievoy fol'gi elektrolizom rasplavlennyh soley. //Cvetnye metally.- 1982.- №2.- s.69-70.
25. Struktura sploshnyh osadkov reniya, poluchennyh elektrolizom hloridnyh rasplavov./ A.N.Baraboshkin, O.N.Vinogradov-Zhabrov, Z.S.Martem'yanova i dr. - Rasplavlennye i tverdye elektrolity.- 1975
26. Eltctrodeposition of rhenium from chloride melts - electrochemical nature, structure and applied aspects./ O.N.Vinigradov-Zhabrov, L.M.Minchenko, N.O.Esina and A.A.Pankratov. Journal of Mining and Metallurgy.- 39 (1-2) B (2003).- p.149-166.
27. Molchanov A.M. Elektroosazhdenie vol'frama iz galogenidnyh rasplavov: Dis. kandidata him.nauk / IVTE UrO RAN. - 1984