Analyzed the influence of structural factors on the activation energy of the radical decomposition of aromatic nitro compounds. The main factor in the reduction of the bond length C-NO 2 and the increase in its dissociation energy is the direct polar conjugation donor substituents with acceptor.
квантово-химический расчет, ароматические нитросоединения, прямое полярное сопряжение, quantum-chemical calculation, aromatic nitro compounds, direct polar conjugation
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