The reactions of electrophilic P(III) chlorides with aliphatic aldehydes are catalized by organic nitrogen bases. The primary intermediates were synthesized with an invironment of P(III): OPCl 2, O 2PCl and O 3P . The reactions are reversible and at heating the intermediates decompouse into aldehyde and P(III) chloride.
альдегид, хлорид P(III), азотистые основания, первичный интермедиат, реакции обратимы, методы ЯМР, aldehyde, P(III) chlorides, nitrogen bases, primary intermediate, the reactions are reversible, NMR methods
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