VZAIMOSVYAZ' HIMICHESKOY STRUKTURY POVERHNOSTI URETANOVYH KAUCHUKOV S POVERHNOSTNYMI ENERGETICHESKIMI I KISLOTNO-OSNOVNYMI HARAKTERISTIKAMI
Abstract and keywords
Abstract (English):
Oscillates specters of surfaces of different makes of carbamates were received by method of infraction total internal reflection of IR- Furie spectroscopy and had bee analyzed. Functional groups which characteristic of carbamate’s surfaces were determinate. Were discovered that, from the standpoint of the acid-base conception of the molecular theory, there were active centers, as the acid nature, so as the base nature on the surface of Carbamates PU-8A, PU-8TB. In common analyze of received experimental data in compression with literature and with free surface energy and acidity parameter’s meanings, of research rubber, which were determinate before, made to reveal intercommunication between surface’s chemical structure and it’s energy and acid-base properties. The received results can be used in regulation the interphase adhesion interaction in compositional material based on the polyurethane rubber s.

Keywords:
уретановые каучуки, ИК-Фурье спектроскопия МНПВО, кислотно-основное взаимодействие, поверхность, Polyurethane rubbers (carbamates), method of infraction total internal reflection of IR-Furie spectroscopy(MITIR of IR- spectroscopy), acid-base interaction, surface
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