Formation of free radicals in the system «hydrogen peroxide – black lead anode» under influence of a constant current has been established by kinetic methods. The rate of reaction of furfural with hydrogen peroxide under conditions of anodic oxidation has been found to slow down in the presence of inhibitors of free radical processes. The constant of ethanol hydroxylation in the system studied has been defined by the method of competitive acceptors and is to be compared with the constants of hydroxylation ethanol by НО . radicals generated from H 2O 2 in the presence of FeSO 4 and VOSO 4 .
пероксид водорода, графитовый анод, свободные радикалы, ингибиторы, метод конкурирующих акцепторов, hydrogen peroxide, black lead anode, free radicals, inhibitors, method of competitive acceptors
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