The process of 1,3-butadiene polymerization in presence of neodymium-based catalyst system was studied. Methods of polymer’s molecular structure modification and catalyst activation were suggested and studied. The samples of polybutadiene with improved molecular, structural, plastic and elastic properties were synthesized.
цис-1,4-полибутадиен, «неодимовая» каталитическая система», модификация, cis-1,4-polybutadiene, neodymium-based catalyst system, modification
1. Z. Zhang, D. Cui, B. Wang, B. Liu, Y. Yang, Struct. Bond. - 2010. - P. 49-108
2. L. Friebe, O. Nuyken, W. Obrecht, Neodymium Based Ziegler/Natta Catalysts and their Application in Diene Polymerization. Springer-Verlag Berlin Heidelberg, 2006. 154 p.
3. B.A. Dolgoplosk, E.I. Tinyakova, VMS., 36(A), 10, 1653-1680 (1994)
4. N.G. Marina, Yu.B. Monakov, Z.M. Sabirov, G.A. Tolstikov, VMS., 33(A), 3, 467-496 (1991)
5. Pat. SSSR 675.866 (1992)
6. Pat. RF 2.141.382 (1999)
7. Pat. RF 2.267.497 (2006)
8. Pat. RF 2.426.747 (2010)
9. Pat. RF 2.422.468 (2011)
10. I.G. Ahmetov, K.M. Kubanov, D.R. Fazilova, E.F. Ziganshina, Kauchuk i Rezina, 5, S. 2-5 (2012)
11. Yu.I. Ermakov, V.A. Zaharov, Uspehi himii, 41, 3, 377-400 (1972)
12. N.M.Chirkov, P.E. Matkovskiy, F.S. D'yachkovskiy, Polimerizaciya na kompleksnyh metallorganicheskih katalizatorah, Himiya, Moskva, 1976. 416 s.
13. K.V. Nel'son, N.N. Novikova, V sb. Kolebatel'nye spektry i molekulyarnye processy v kauchukah, Himiya, Leningrad, 1965. S. 5-43
14. I.G. Ahmetov, N. Mahiyanov, I.I. Salahov, A.S. Hachaturov, Kauchuk i Rezina, 5, 2-5 (2007)
15. I.G. Ahmetov, V.G. Kozlov, I.I. Salahov, A.G. Sahabutdinov, G.S. D'yakonov, Kauchuk i rezina, 3, 7-10 (2009)
16. I.G. Ahmetov, D.R. Ahmetova, I.I. Salahov, A.G. Sahabutdinov, V.G. Kozlov, Kauchuk i rezina, 1, 9-11 (2010)
17. I.G. Ahmetov, D.R. Ahmetova, Kauchuk i rezina, 5, 2-5 (2010)
18. K.M. Kubanov, D.R. Ahmetova, I.G. Ahmetov, III Konferenciya molodyh uchenyh, posvyaschennaya mezhdunarodnomu godu himii (Nizhnekamsk, Rossiyamarta 2011). Nizhnekamsk, 2011, S. 50-51.
