REAKCII ALIFATIChESKIH AL'DEGIDOV S HLORIDAMI P(III). VII. REAKCII PERVIChNYH INTERMEDIATOV S HLORIRUYuSchIMI REAGENTAMI

Karimova R F; Gazizov M B; Hayrullin R A; Burangulova R N; Nikitin V G

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Home / Journals / Herald of Technological University / Volume 16 Issue 6 / REAKCII ALIFATIChESKIH AL'DEGIDOV S HLORIDAMI P(III). VII. REAKCII PERVIChNYH INTERMEDIATOV S HLORIRUYuSchIMI REAGENTAMI

REAKCII ALIFATIChESKIH AL'DEGIDOV S HLORIDAMI P(III). VII. REAKCII PERVIChNYH INTERMEDIATOV S HLORIRUYuSchIMI REAGENTAMI

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REAKCII ALIFATICHESKIH AL'DEGIDOV S HLORIDAMI P(III). VII. REAKCII PERVICHNYH INTERMEDIATOV S HLORIRUYUSCHIMI REAGENTAMI

Journal: HERALD OF TECHNOLOGICAL UNIVERSITY Volume 16 № 6 , 2025

Rubrics: STRUKTURA VESCHESTVA I TEORIYA HIMICHESKIH PROCESSOV

UDC 546.18.131 + 547. 594.1

Karimova R F ¹

Gazizov M B ²

Hayrullin R A ³

Burangulova R N ⁴

Nikitin V G ⁵

Author and publication information

Authors:

1. KNITU

2. KNITU

3. KNITU

4. KNITU

5. KNITU

Type:

Article

eLocation:

Status:

Published

Received:

19.04.2023

Accepted:

01.08.2025

Published:

01.08.2025

Subject area:

UDC 546.18.131 + 547. 594.1

Language:

Russian

Keywords:

первичный интермедиат, хлорирующие реагенты, хлорфосфаты, полные фосфаты, лигандный обмен, квазифосфониевый центр, primary intermediates, chlorinating reagents, chlorophosphates, full phosphates, ligand exchange, quasiphosphonium center

Abstract and keywords

Abstract (English):
The primary intermediates of the reactions of the aliphatic aldehydes with P(III) chlorides react easily with the chlorinating reagents – phosphorus pentachloride and gaseous chlorine. In addition to chlorophosphates the full phosphates are also formed as a result of ligand exchange at quasiphosphonium center.

Keywords:
первичный интермедиат, хлорирующие реагенты, хлорфосфаты, полные фосфаты, лигандный обмен, квазифосфониевый центр, primary intermediates, chlorinating reagents, chlorophosphates, full phosphates, ligand exchange, quasiphosphonium center

References

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