The dependences which describe link of molecular mass and polydispersity index of polystyrene synthesized to “living” radical polymerization on the adition-fragmentation type, with operating parameters of process (temperature, initial monomer concentrations, initiator and agent of reversible chain transfer) have been received by method of numerical experiment.
контролируемая радикальная полимеризация, коэффициент полидисперсности, молекулярная масса, полистирол, controlled radical polymerization, molecular mass, polydispersity index, polystyrene
1. Handbook of RAFT Polymerization / ed. by C. Barner-Kowollik. Weinheim.: Wiley-VCH Verlag GmbH, 2008. 556 p.
2. Zetterlund P.B. RAFT polymerization under microwave irradiation: Toward mechanistic understanding / P.B Zetterlund, S. Perrier // Macromolecules. 2011. V. 44. № 6. R. 1340-1352.
3. Ulitin N.V. Izuchenie vliyaniya upravlyayuschih faktorov na molekulyarno-massovye harakteristiki polistirola, poluchaemogo psevdozhivoy radikal'noy polimerizaciey / N.V. Ulitin, A.V. Oparkin, R.R. Nabiev // Vestnik Kazanskogo tehnologicheskogo universiteta. 2012. № 22. S. 80-81.
4. Ulitin N.V. Kineticheskaya model' processa radikal'noy polimerizacii butilakrilata v prisutstvii tritiokarbonatov / N.V. Ulitin, D.Sh. Kalinina, V.A. Sidel'nikova, T.R. Deberdeev // Vestnik Kazanskogo tehnologicheskogo universiteta. 2012. № 21. S. 67-70.