ISSLEDOVANIE «POVEDENIYA» MOLEKULYARNO-MASSOVYH HARAKTERISTIK POLISTIROLA, POLUCHAEMOGO METODOM «ZHIVOY» RADIKAL'NOY POLIMERIZACII, V ZAVISIMOSTI OT HIMICHESKIH I FIZICHESKIH VOZDEYSTVIY NA REAKCIONNUYU SISTEMU
Abstract and keywords
Abstract (English):
The dependences which describe link of molecular mass and polydispersity index of polystyrene synthesized to “living” radical polymerization on the adition-fragmentation type, with operating parameters of process (temperature, initial monomer concentrations, initiator and agent of reversible chain transfer) have been received by method of numerical experiment.

Keywords:
контролируемая радикальная полимеризация, коэффициент полидисперсности, молекулярная масса, полистирол, controlled radical polymerization, molecular mass, polydispersity index, polystyrene
References

1. Handbook of RAFT Polymerization / ed. by C. Barner-Kowollik. Weinheim.: Wiley-VCH Verlag GmbH, 2008. 556 p.

2. Zetterlund P.B. RAFT polymerization under microwave irradiation: Toward mechanistic understanding / P.B Zetterlund, S. Perrier // Macromolecules. 2011. V. 44. № 6. R. 1340-1352.

3. Ulitin N.V. Izuchenie vliyaniya upravlyayuschih faktorov na molekulyarno-massovye harakteristiki polistirola, poluchaemogo psevdozhivoy radikal'noy polimerizaciey / N.V. Ulitin, A.V. Oparkin, R.R. Nabiev // Vestnik Kazanskogo tehnologicheskogo universiteta. 2012. № 22. S. 80-81.

4. Ulitin N.V. Kineticheskaya model' processa radikal'noy polimerizacii butilakrilata v prisutstvii tritiokarbonatov / N.V. Ulitin, D.Sh. Kalinina, V.A. Sidel'nikova, T.R. Deberdeev // Vestnik Kazanskogo tehnologicheskogo universiteta. 2012. № 21. S. 67-70.

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