RASCHET SREDNIH TOPOLOGICHESKIH PARAMETROV POLIBUTILAKRILATA ISHODYA IZ KINETICHESKOY MODELI PROCESSA EGO SINTEZA – «ZHIVOY» RADIKAL'NOY POLIMERIZACII V REZHIME OBRATIMOY PEREDACHI CEPEY PO MEHANIZMU «PRISOEDINENIYA-FRAGMENTACII»
Authors:
1.
KNITU
2.
KNITU
3.
KNITU
4.
KNITU
5.
KNITU
6.
KNITU
Type:
Article
eLocation:
Status:
Published
Received:
19.04.2023
Accepted:
01.08.2025
Published:
01.08.2025
Subject area:
UDC 541(64+127) : 547.538.141
Language:
Russian
Keywords:
численный эксперимент, обратимая передача цепи, полибутилакрилат, управляющий фактор, computing experiment, operating factor, polybutyl acrylate, reversible chain transfer
Abstract (English):
The dependences of average topological parameters of polybutyl acrylate synthesized by the method of “living” radical polymerization in mode of reversible chain transfer by “addition-fragmentation” mechanism, on temperature of polymerization, initial concentrations of the monomer, the reversible chain transfer agent, the initiator (2,2 ’-azobisisobutyronitrile) have been defined. A number of computing experiments for the purpose to determine influence of operating factors on average topological parameters of polybutyl acrylate has been carried out.
The dependences of average topological parameters of polybutyl acrylate synthesized by the method of “living” radical polymerization in mode of reversible chain transfer by “addition-fragmentation” mechanism, on temperature of polymerization, initial concentrations of the monomer, the reversible chain transfer agent, the initiator (2,2 ’-azobisisobutyronitrile) have been defined. A number of computing experiments for the purpose to determine influence of operating factors on average topological parameters of polybutyl acrylate has been carried out.
Keywords:
численный эксперимент, обратимая передача цепи, полибутилакрилат, управляющий фактор, computing experiment, operating factor, polybutyl acrylate, reversible chain transfer
численный эксперимент, обратимая передача цепи, полибутилакрилат, управляющий фактор, computing experiment, operating factor, polybutyl acrylate, reversible chain transfer
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2. Ulitin N.V. Izuchenie vliyaniya upravlyayuschih faktorov na molekulyarno-massovye harakteristiki polistirola, poluchaemogo psevdozhivoy radikal'noy polimerizaciey / N.V. Ulitin, A.V. Oparkin, R.R. Nabiev // Vestnik Kazanskogo tehnologicheskogo universiteta. 2012. № 22. S. 80-81.
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