MODELIROVANIE RAVNOVESIY V SISTEME CUSO 4 – H 2O – (NH 4) 2SO 4 – OH ‑ PRI MALYH KONCENTRACIYAH CUSO 4 NA OSNOVE EKSPERIMENTA PO OSTATOCHNOY KONCENTRACII, POTENCIOMETRICHESKOGO TITROVANIYA I IZMERENIYA PH GIDROLIZA (SOOBSCHENIE 1)
Abstract and keywords
Abstract (English):
The algorithm for the calculation of equilibrium constants in systems containing a lot of precipitations was suggested. For the calculation of the formation of precipitation areas used four conditions saturation of the solution: 1. Rule of solubility 2. Rule molecular solubility 3. Rule solubility intermediates, 4. The condition of the sedimentation priority. This methodology is used to construct a mathematical model of the equilibrium in the system Cu SO 4 – H 2O – OH – as the function of pH and the concentration Sn(II) . A mathematical model of the system is designed to optimize the synthesis of desired compounds.

Keywords:
равновесия, водные растворы, осадки соединений меди(II), рентгенофлуоресцентный анализ, сульфат меди, equilibrium, aqueous solutions, precipitation of Cu(II) compounds, X-ray fluorescence analysis, copper sulfate
References

1. Yusupov R.A., Bahteev S.A. Raschet oblastey vydeleniya tverdyh faz v sistemah ion metalla - voda - kompleksoobrazuyuschiy agent // Zhurn. fiz. himii. 2009. T.83. №12. S.2395-2397.

2. Yusupov R.A., Bahteev S.A., Smerdova S.G. Raschet oblastey suschestvovaniya osadkov v sistemah ion metalla - N2O - kompleksoobrazuyuschiy agent s uchetom rastvorimosti intermediatov // Zhurn. fiz. himii. 2010. T.84. №7. S.1391-1393.

3. Yusupov R.A., Bahteev S.A., Gatiyatullin I.R. Metodika vypolneniya izmereniy koncentracii serebra v tehnologicheskih vodah predpriyatiy // Vestnik Kazan. tehnol. un-ta. 2012. №6.

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