![KOMPLEKSNYE SOEDINENIYa GIDROKSIPROIZVODNOGO DINITROBENZOFUROKSANA. Chast' 1. SPEKTRAL'NYE ISSLEDOVANIYa KOMPLEKSOV NA OSNOVE trihlorida RODIYa I DINATRIEVOGO KOMPLEKSA 4,6-DINITRO-1-OKSOBENZ[6,5-C]-2,1,3-OKSADIAZOLDIOLA-5,7](/upload/21232f297a57a5a743894a0e4a801fc3/journals/cover/95166a87c76a31158ddbba941da1ca51.jpeg)
By IR spectroscopy indicated that the complexation of rhodium trichloride with 4,6-dinitro-1-oxobenz[6,5-c] -2,1,3-oxodiazoldiol-5, 7 in an aqueous medium and a water-acetone medium furaxane cycle is stored; molecule ligand coordinated to the rhodium ion by the furaxane cycle’s nitrogen atom and one oxygen atom from nitrogroup. In the complexes are present terminal ( Rh-Cl ) and bridging ( Rh-Cl-Rh ) binds; coordinated and crystal water; ( π - π ) interaction rhodium ions with ligand’s aryl ring. The complex consists of several ligand molecules with different orientations in space. Polyligand-polynuclear structure was established and provided high thermal stability.
гидроксипроизводные динитробензофураксана, динатриевый комплекс 4,6-динитро-1-оксобенз[6,5-c]-2,1,3-оксадиазолдиола-5,7, трихлорид родия, комплексообразование, синтез, водная среда, водно-ацетоновая среда, спектральные исследования, dinitrobenzofuroxane hydroxyderivatives, disodium 4,6-dinitroо-1-oxobenz[6,5-c]-2,1,3-oxadiazoldiole-5,7 complex, rhodium trichloride, complexing, synthesis, aqueous medium, aqueous -acetone medium, spectral studies
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