This paper describes a reaction of Langmuir-Blodgett films of a number of thiacalix[4]arenes to the presence of silver nitrate in subphase. The analysis of Langmuir isotherms of the thiacalix[4]arenes films was provided. It was found that only tetra-cyanopropoxy-tetra-p-tert-butylthiacalix[4]arene forms hard-condensed film on the water surface. All tested thiacalix[4]arenes form hard film on the surface, if subphase is aqueous silver nitrate solution. Langmuir-Schaeffer transfer of the films both from water and aqueous solution of AgNO 3 on a solid substrate ITO was carried out. Changes in the structure of the films transferred from water subphase after AgNO 3 addition were studied using atomic force microscopy.
тиакаликс[4]арены, пленки Ленгмюра-Блоджетт, изотермы Ленгмюра, атомно-силовая микроскопия, thiacalix[4]arenes, Langmuir–Blodgett films, Langmuir isotherm, atomic force microscopy
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