On the base of kinetic model of controlled radical RAFT-polymerization and predictive model of properties’ complex (glass transition temperature, thermal expansion coefficients, dielectric permittivity) was made numerical experiment of controlling factors’ influence on these polybutilenacrylate’s properties estimation.
диэлектрическая проницаемость, контролируемая радикальная полимеризация, коэффициенты теплового расширения, модель, обратимая передача цепи, полибутилакрилат, температура стеклования, controlled radical polymerization, dielectric permeability, glass-transition temperature, model, polybutilenacrylate, reversible transfer of chain, thermal expansion coefficients
1. Ulitin N.V. Kineticheskaya model' processa radikal'noy polimerizacii butilakrilata v prisutstvii tritiokarbonatov / Ulitin N.V., D.Sh. Kalinina, V.A. Sidel'nikova, T.R. Deberdeev // Vestnik Kazanskogo tehnologicheskogo universiteta. - 2012. - №21. - C. 67-70.
2. Oparkin A.V. Zavisimost' teplofizicheskih i dielektricheskih svoystv polistirola ot koncentracionnyh i teplovyh vozdeystviy na radikal'no polimerizuyuschuyusya s obratimoy peredachey cepey (tip «prisoedinenie-fragmentaciya») reakcionnuyu sistemu / A.V. Oparkin, I.I. Nasyrov, V.A. Sidel'nikova, N.V. Ulitin, R.Ya. Deberdeev // Vestnik Kazanskogo tehnologicheskogo universiteta. - 2013. № 7. S. 121-126.
3. Askadskii A.A. Computational Materials Science of Polymers. Cambridge, Cambridge International Science Publish. 2003. 650 p.
4. Fox, T.G. Second-order transition temperatures and related properties of polystyrene. Influence of molecular weight / T.G. Fox, P.J. Flory // J. Appl. Phys. - 1950. - V. 21, No. 6. - P. 581-592
5. Van Krevelen D.W. Properties of polymers. Amsterdam. Elsevier, 1990. 875 p.
