T he kinetics of cracks growth in synthetic isoprene rubber (SIR-3) vulcanizates in the atmosphere of ozone was studied by the method of optical microscopy. The average value of cracks surface was used as a measure of the degree of cracking. The growth of surface cracks involves two stages: a relatively slow in the beginning and faster, which is flowing at a constant rate. An empirical relationships that describe this process at different concentrations of ozone were proposed. A physical interpretation of the constants appearing in the empirical relationships was given.
трещины, озон, кинетика, механизм, вулканизаты, полиизопрен, cracks, ozone, kinetics, mechanism, vulcanizates, polyisoprene
1. Cataldo F. The action of ozone on polymers having unconjugated and cross- or linearly conyugation: chemistry and technological aspects. Polym. Degrad. and Stab., 2001,v.73, p. 511-520.
2. Podmaster'ev V.V. «Kineticheskie zakonomernosti rastreskivaniya elastomerov pod deystviem ozona», Diss. … kand. him.nauk. M.: IBHF im.N.M.Emanuelya RAN, 2008. - 114 s.
3. Huang D., La Count B.J., Castro J.M., Ignatz-Haver F. Development of a service simulating, accelerated method for exterior tire rubber compounds. Polym. Degrad. and Stab., 2001,v.74, p. 353-362.
4. Tuzhikov O.O., Mednikov S.V., Sychev N.V., Suvorina S.V., Ol'shanskiy O.V. , Zheltobrohova V.F. «Vliyanie recepturno-tehnologicheskih faktorov na ozonostoykost' vulkanizatov», Mezhdunarodnaya nauchno-prakticheskaya konferenciya «Rezinovaya promyshlennost'. Syr'e, materialy,Tehnologii. M.21-25.5.12. s.154.
5. KruzlakJ., Hudec I., Dosoudil R. Influence of Polym. Degrad. and Stab., 2001,v.73, p. 511-520. Thermo-oxidative and ozone aging on the properties of elastomeric magnetic composites. Polym. Degrad. and Stab., 2012, v.97, p. 921-928.
6. Razumovskiy S.D., Podmaster'ev V.V., Zaikov G.E. Dokl. Akad. Nauk SSSR, 268(1), 129 (1983).
7. Razumovskiy S.D., Podmaster'ev V.V., Zaikov G.E. Vysokomolek.soed., A, 25 (8), 1173 (1983).