Isolated and exchange couplied dialkylated Ti(III) ions in the TiCl 4 + TIBA system was observed by ESR spectroscopy method. The orbital ordered of exchange couplied Ti(III) ions in associates was observed .
трехвалентный титан, алкилированные ионы титана, ЭПР, орбитальное упорядочение, three- valence titanium, alkylated ions of titanium, ESR, orbital ordered
1. E. Chaushesku, Stereospecificheskaya polimerizaciya izoprena. Himiya, Moskva, 1981. 256 s.
2. X Kuska, EPR perehodnyh metallov. Mir, Moskva, 1970. 219 s.
3. S.A.Al'tshuler, B.M.Kozyrev, Elektronnyy paramagnitnyy rezonans soedineniy elementov promezhutochnyh grupp. Nauka, Moskva, 1972. 672 c.
4. E.V.Biktagirova, V.V.Biktagirov, Vestnik Kazan. tehnol. un-ta, 11, 7- 10 (2012).
5. V.V. Zaharov, V.F. Anufrienko, T.F. Filatova, V.S. Savel'eva, R.H. Sadykov, Dokl. AN SSSR, 308, 5, 1170- 1173 (1989).
6. N.A. Isakov, G.A. Belova, V.S. Fihtengol'c, Kontrol' proizvodstva sinteticheskih kauchukov. Himiya, Leningrad, 1980. 240 s.
7. I.V. Garmonov, Sinteticheskiy kauchuk. Himiya, Leningrad, 1983. 560 s.
8. N.G. Maksimov, G.A. Nesterov, V.A. Zakharov, V.F. Anufrienko, Yu.I. Yermakov. React. Kinet. Catal. Lett., 8, 1, 81-85 (1978).
9. N.G. Maksimov, G.A. Nesterov, V.A. Zakharov, P.V. Stchastnev, V.F. Anufrienko, Yu.I. Yermakov, J. of Mol. Catal., 4, 167-179 (1978).
10. A. Kerrington, E. Mak- Lechlan, Magnitnyy rezonans i ego primenenie v himii. Mir, Moskva, 1970. 447 c.
11. E.V.Biktagirova, V.K.Polovnyak, V.V.Biktagirov, Vestnik Kazan. tehnol. un-ta, 6, 7-11 (2008).
12. D. Reinen, C. Friebel, Struct. Boding., 37, 1-60 (1979).
