Thermal degradation of cured stocks of polyisoprene in a gaseous fluid of air, an argon, a carbon dioxide is investigated. It is revealed that at temperature magnification in from 600 to 700 O C the fraction of gaseous fraction grows in реде air and an argon, in the presence of a carbon dioxide this fraction is slashed twice, promoting formation carbon. Carbon dioxide application confines formation of polycyclic aromatic hydrocarbons.
1,4-цис полиизопрен, резина, термодеструкция, резиновые смеси, релаксация, 1,4-cis polyisoprene, rubber, thermal degradation, rubber stock, relaxation
1. W. Kaminsky, C. Mennerich, Z. Zhang, J. Anal. Appl. Pyr., 85, 1-2, 334-337 (2009)
2. M. M. Barbooti, T. J. Mohamed, A. A. Hussain, F. O. Abas, J. Anal. Appl. Pyr., 72, 1, 165-170 (2004)
3. S. Ucar, S. Karagoz, J. Yanik, Fuel Proc. Tech, 87, 1, 53-58, (2005).
4. H. Pakdel, D. M. Pantea, C. Roy, J. Anal. Appl. Pyr., 57, 1, 91-107, ( 2001)
5. M. J. Hackathorn, M. J. Brock, J. of Pol. Sci. Part B: Pol. Lett., 8, 9, 617-625, (1970)
6. J. Xigao, L. Huiming, J. Anal. Appl. Pyr., 3, 1, 49-57, (1981).
7. F. Chen, J. Qian, Fuel, 81, 16. 2071-2077, (2002).
8. O.A. Korobeynikova, TB. Minigaliev, V.P. Dorozhkin, Vestnik KGTU, 14, 11, 195-201,(2011).
9. T.B. Minigaliev, O.A. Korobeynikova, V.P. Dorozhkin, Vestnik KGTU, 15, 18, 144-146, (2012).



