KINETICHESKIE OSOBENNOSTI PREVRASCHENIYA NITRATOV CELLYULOZY V VODNOM RASTVORE AMMIAKA
Abstract and keywords
Abstract (English):
We have studied the characteristics of various nitrate cellulose in water solution (2-10%) of ammonium hydroxide at 40-90 0 C . The peculiarity of kinetics of nitrate cellulose ammonolise is the NO 2 formation in a solution with a velocity of its accumulating twice of that of the reactions leading to NO 3 formation. Such nitrate cellulose transformation is agreed quite good with the known peculiarities of an alkaline hydrolysis of liquid nitroethers and nitrate cellulose.The knowledge of kinetics and mechanism of nitrate cellulose in an ammonia aqueous solution gives the possibility of a reliabie prediction of denitration and destruction under various conditions.

Keywords:
раствор аммиака, вязкость раствора, нитрат целлюлозы, кинетика деструкции, ammonia aqueous solution, nitrate of cellulose, viscosity of solution, kinetics of destruction
References

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