POBOCHNYE REAKCII GETEROGENNOGO ACETILIROVANIYA CELLYULOZY PRI POLUCHENII TRIACETATA CELLYULOZY DLYA SPECIAL'NOY TEHNIKI
Authors:
1.
KNITU
2.
KNITU
3.
KNITU
Type:
Article
Pages:
from 89
to 91
Status:
Published
Received:
19.04.2023
Accepted:
01.08.2025
Published:
01.08.2025
Subject area:
UDC 541.164:543.422.23
Language:
Russian
Keywords:
ацетилирование, триацетат целлюлозы, хлорная кислота, побочные реакции, acetylation, cellulose triacetate, perchloric acid, side reactions
Abstract (English):
Analysis of possibility of replacing toxic benzene to less toxic xylene in a heterogeneous technology cellulose triacetate was conducted. The regularities of the heterogeneous acetylation of cellulose with acetic anhydride, acetic acid and xylene in the presence of perchloric acid catalyst was considered. The possibility of side reactions was defined. The conclusion about the need to consider side-reactions with the O-acylation of cellulose was made.
Analysis of possibility of replacing toxic benzene to less toxic xylene in a heterogeneous technology cellulose triacetate was conducted. The regularities of the heterogeneous acetylation of cellulose with acetic anhydride, acetic acid and xylene in the presence of perchloric acid catalyst was considered. The possibility of side reactions was defined. The conclusion about the need to consider side-reactions with the O-acylation of cellulose was made.
Keywords:
ацетилирование, триацетат целлюлозы, хлорная кислота, побочные реакции, acetylation, cellulose triacetate, perchloric acid, side reactions
ацетилирование, триацетат целлюлозы, хлорная кислота, побочные реакции, acetylation, cellulose triacetate, perchloric acid, side reactions
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