With allowance for interdependent processes of heat transfer and chemical reaction was calculated heat balance of polymerization reactor mixing for carrying out the synthesis of polystyrene by the method of RAFT-polymerization. Determined values of the heat transfer coefficients of laboratory reactor under different conditions of synthesis carrying. Adequacy of the developed mathematical model of interdependent processes of heat transfer and chemical reaction proceeding in the mixing reactor in the styrene RAFT-polymerization is shown by comparison of calculated and experimental value of polystyrene molecular-mass characteristics.
контролируемая радикальная полимеризация, математическая модель, полистирол, тепловой баланс, RAFT-полимеризация, Controlled radical polymerization, mathematical model, polystyrene, thermal balance, RAFT-polymerization
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