Abstract – A mathematical model is proposed which describes kinetics of cationic copolymerization of isobutylene with isoprene in the presence of aluminum trichloride catalyst in methyl chloride medium. Reverse kinetic problem is solved for determining of unknown kinetic rate constants of the elementary reactions. The adequacy of the model is demonstrated by comparison of model-calculated product molecular-mass properties against those values which are obtained through experiments.
сополимеризация, быстрые жидкофазные процессы, бутилкаучук, cationic polymerization, butyl rubber, molecular-mass characteristics, the rate constants of elementary reactions
1. Kafarov V.V. Matematicheskaya model' processa suspenzionnoy sopolimerizacii / Izvestiya vuzov. Himiya i himicheskaya tehnologiya. - 1976. - T. 19, №9. - S. 1423-1428.
2. Kuchanov S.I. Matematicheskoe modelirovanie sopolimerizacii / Matematicheskoe modelirovanie. - 1991. - T.5, №5. - S. 110-12.
3. Myagchenkov V.A. Problemy kinetiki i topologii geterofaznoy sopolimerizacii. - 1973. - T. 42, №5. - S. 827-853.
4. Ibragimli D.Sh. Identifikaciya processa polimerizacii pri razrabotke ASU TP proizvodstva butilkauchuka / Izvestiya vuzov. Neft' i gaz. - 1985. -№7. - S. 86-90.
5. Sangalov Yu.A. Polimery i sopolimery izobutilena: Fundamental'nye problemy i prikladnye aspekty. Ufa: Gilem, 2001. 384 s.
6. Aminova G.A. Matematicheskoe modelirovanie processa sinteza butilkauchuka // Vestnik Kazanskogo nacional'no issledovatel'skogo tehnologicheskogo universiteta. - 2012. - T. 21, №7. - S. 103-106.
7. Yasuyuki Tanaka // Progress in Polymer Science. 1989. V. 14. Iss. 3. P. 339-371.
8. Sven K.-H. // Journal of Macromolecular Science, Part C: Polymer Reviews. 2003. Vol. C43. Iss. 4. P. 581-628.
9. Fengfu Li // Journal of Macromolecular Science, Part A: Pure and Applied Chemistry. 1994. Vol. A31. Iss. 2. P. 273-282.
10. Gyor M. // Journal of Macromolecular Science: Part A: Pure and Applied Chemistry. 1984. Vol. A21. Iss. 10. P. 1323-1338.
11. Orlinkov A. V. // Russian Chemical Bulletin. 1996, Vol. 45, Iss. 5, P. 1124-1127.
12. Berlin Al. Al. // Polymer-Plastics Technology and Engineering. 1991. Vol. 30, Iss. 2-3, P. 253-297.
13. Kennedy J. P. // Journal of Macromolecular Science: Part A:Pure and Applied Chemistry. 1982. Vol. A18. Iss. 1. P. 129-152.
14. Sigwalt P. // Progress in Polymer Science. 2006. Vol. 31, Iss. 1, P. 44-120.
15. Pat. 192498 Rossiyskaya Federaciya, S 08 F 25/01 Sposob polucheniya butilkauchuka / S.I. Salyh-zade, N.T. Sultanov i dr. - zayavl. 19.07.1965; opubl. 10.11.1967.
16. Pat. 480725 Rossiyskaya Federaciya, S 08 F 3/14 Sposob polucheniya poliizobutilena/ Yu.A. Sangalov, N.V. Gazeeva i dr. - zayavl. 08.01.1974; opubl. 02.05.1976.
17. Pat. 579769 Rossiyskaya Federaciya, 6 S 08 F 210/12, 2/38 Sposob polucheniya polimerov ili sopolimerov izobutilena / N.A. Konovalenko, V.S. Byrihin i dr. - zayavl. 28.05.1976; opubl. 27.01.1995.
18. Kennedi Dzh. Kationnaya polimerizaciya. Per. s angl. pod red. P. Plesha. Moskva: Mir, 1966.584 s.
19. Biesenberger, J.A.// Principles of polymerization engineering. New York: John Wiley & Sons, Inc., 1983. P. 744.
20. Usmanov T.S. Obratnye zadachi formirovaniya molekulyarno-massovyh raspredeleniy. Moskva: Himiya, 2004. 252 s.
21. Puskas J.E. // Journal of Macromolecular Science: Part A. 1991, Vol. A28. Iss. 1. P. 65-80.
22. Markina E.A. Sintez butilkauchuka s ispol'zovaniem modificirovannoy kataliticheskoy sistemy na osnove hloristogo alyuminiya: avtoref. dis. kand. him. nauk: 18.03.2010, 21.04.2010 / Markina. - Kazan', 2010. S.19.
23. Merzhanov A.G. Neizotermicheskie yavleniya i processy. Chernogolovka: «Isman», 2006. 56 s.
24. Pavlov K.F. Primery i zadachi po kursu processov i apparatov himicheskoy tehnologii. L: «Himiya», 1987. 576 s.
25. Spravochnik himika (v 7 tomah), 2-e izdanie - M: «Himiya», 1968.
26. Kuchanov S.I. Metody kineticheskih raschetov v himii polimerov. Moskva: «Himiya», 1978. 368 s.
