In this paper two-component mixture pervaporation were simulated by modified dual control volume grand canonical molecular dynamic method. Considered the effect of the interaction with the membrane, the pressure and concentration on the flow and selectivity. It has been shown that pressure has little effect on the flow quantity. The studied membranes exhibit greater selectivity for substance interacts strongly with the membrane.
первапорация, метод контрольных объемов, селективность, межмолекулярное взаимодействие, pervaporation, DCV-GCMD, selectivity, intermolecular interaction
1. M. Mudler, Vvedenie v membrannuyu tehnologiyu. Mir, Moskva, 1999, 513 s.
2. W. Kujawski, Pol. J. Environ. Stud., 9, 1, 13-26 (2000)
3. H. Ahn, H. Lee, S.-B. Lee, Y. Lee, Desalination, 193, 244-251 (2006)
4. R. Kreiter, D. Wolfs, C. Engelen, H. Vanveen, J. Vente, J. Membr. Sci., 319, 126-132 (2008)
5. K. Sato, T. Nakane, J. Membr. Sci., 301, 151-161 (2007)
6. K.-H. Lee, H.-K. Kim, J.-W. Rhim, J. Appl. Polym. Sci., 58, 10, 1707-1712 (1995)
7. S.S. Dhaval, Doctoral dissertations, University of Kentucky, Kentucky, 2001, 301 p.
8. J.Z. Yang, Q.L. Liu, H.T. Wang, J. Membr. Sci., 291, 1-9 (2007)
9. E.M. Flanigen, J.M. Bennett, R.W. Grose, J.P. Cohen, R.L. Patton, R.M. Kirchner, J.V. Smith, Nature, 271, 512-516 (1978)
10. G.S. Heffelfinger, F. van Swol, J. Chem. Phys., 100, 10, 7548 (1994)
11. Z. Wu, Z. Liu, W. Wang, Y. Fan, N. Xu, Chin. J. Chem. Eng., 16, 5, 709-714 (2008)
12. M.I. Farahov, A.V. Klinov, F.M. Velterop, V.A. Maryahina, R.R. Akberov, N.N. Maryahin, A.V. Malygin, A.R. Fazlyev, Vestnik Kazanskogo Tehnologicheskogo Universiteta, 15, 11, 166-168 (2012)
13. I.P. Anashkin, A.V. Klinov, Vestnik Kazanskogo Tehnologicheskogo Universiteta, 16, 19, 7-13 (2013)
14. X. Feng, R.Y.M. Huang, J. Membr. Sci., 92, 3, 201-208 (1994).
