A nanofiller disperse particles aggregation process in elastomeric matrix has been studied. The modified model of irreversible aggregation particle-cluster was used for this process theoretical analysis. The modification necessity is defined by simultaneous formation of a large number of nanoparticles aggregates. The offered approach allows to predict nanoparticles aggregates final parameters as a function of the initial particles size, their contents and other factors number.
Nanocomposite, elastomer, nanoparticle, aggregation, diffusion, нанокомпозит, эластомер, наночастица, агрегация, диффузия
1. G.V. Kozlov, Yu.G. Yanovskii, G.E. Zaikov: Structure and Properties of Particulate-Filled Polymer Composites: the Fractal Analysis. New York, Nova Science Publishers, Inc., 2010. 282 p.
2. Sapayev Kh. Kh, Musov I. V., Kozlov G. V., Zaikov G. E., Mikitaev A. K. Teoreticheskoe opisanie teplostoikosti nanokompozitov polyvinilchloridniy plasticat/organoglina // Vestnik Kazanskogo technologicheskogo universiteta, 2013. №20. PP. 93-97
3. Sapayev Kh. Kh, Musov I. V., Kozlov G. V., Zaikov G. E., Mikitaev A. K. Vliyanie molekuliarnich characteristic polymernoy matritsy na steepen usileniya nanokompositov polimer/organoglina // Vestnik Kazanskogo technologicheskogo universiteta, 2013. №20. PP. 104-107
4. D.C. Edwards: Polymer-filler interactions in rubber reinforcement. J. Mater. Sci., 25 (12), 4175 (1990).
5. A.K. Mikitaev, G.V. Kozlov, G.E. Zaikov: Polymer Nanocomposites: the Variety of Structural Forms and Applications. New York, Nova Science Publishers, Inc., 2008. 319 p.
6. A.L. Buchachenko: The nanochemistry - direct way to high technologies of new century. Uspekhi Khimii, 72 (5), 419 (2003).
7. G.V. Kozlov, Yu.G. Yanovskii, A.I. Burya, Z.Kh. Aphashagova: Structure and properties of particulate-filled nanocomposites phenylone/aerosol. Mekhanika Kompozitsionnykh Materialov i Konstruktsii, 13 (4),479 (2007).
8. T.A. Witten, P. Meakin: Diffusion-limited aggregation at multiple growth sites. Phys. Rev. B, 28 (10), 5632 (1983).
9. T.A. Witten, L.M. Sander: Diffusion-limited aggregation. Phys. Rev. B, 27 (9), 5686 (1983).
10. A.N. Bobryshev, V.N. Kozomazov, L.O. Babin, V.I. Solomatov: Synergetics of Composite Materials. Lipetsk, NPO ORIUS, 1994. 154 p.
11. N. Sheng, M.C. Boyce, D.M. Parks, G.C. Rutledge, J.I. Abes, R.E. Cohen: Multiscale micromechanical modeling of polymer/clay nanocomposites and the effective clay particle. Polymer,45 (2), 487 (2004).
12. J. Happel, G. Brenner: The Hydrodynamics at Small Reynolds Numbers. Moscow, Mir, 1976. 418 p.
13. N.J. Mills: The rheology of filled polymers. J. Appl. Polymer Sci., 15 (11), 2791 (1971).
