EVOLYUCIYA MOLEKULYARNO-MASSOVOGO RASPREDELENIYA POLIDIENOV PRI POLIMERIZACII NA POLICENTROVYH KATALIZATORAH CIGLERA-NATTA
Abstract and keywords
Abstract (English):
In the framework of mathematical modeling was used Monte-Carlo method to determine the kinetic parameters of polybutadiene polymerization during Ziegler-Natta catalysts. Was shown that depending on monomer conversion, macro-chains growth occurs on the various types of active centers, which affects on the character of molecular weight distribution of producing polymer.

Keywords:
катализаторы Циглера-Натта, полицентровые катализаторы, математическое моделирование, метод Монте-Карло, Ziegler-Natta catalysts, multi-site catalyst, mathematical modeling, Monte-Сarlo method
References

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