Interaction of dialkylphosphorous acids with N-tert-butyl-2,2-dichloropropaneimine leads to the formation of addition products on imine group. They form corresponding picrates. The addition products with chloromethylene group react with methanolic solution of sodium methylate forming the phosphorylated aziridines, but with dichoromethylene group - phosphorylated enamine. Addition product trifluoroacetate transforms into betaine.
диалкилфосфористые кислоты, N-трет-бутил-2,2-дихлорпропанимин, продукт присоединения, пикриновая и трифторуксусная кислоты, пикраты, фосфорилированные енамины, бетаин, спектры ЯМР 1Н и 3Р, dialkylphosphorous acids, 2,2-dichloropropaneimine, addition product, picric and trifluoroacetic acids, picrates, phosphorylated enamines, betaine, 1Н и 3Р NMR spectra
1. Hayrullin R.A. Reakcii alifaticheskih al'degidov s hloridami R(III). I. Novyy podhod k issledovaniyu vzaimodeystviya alifaticheskih al'degidov s elektrofil'nymi hloridami R(III) / R.A. Hayrullin, M.B. Gazizov, R.F. Karimova, R.R. Karimov, N.N. Gazizova // Vestnik KTU. - 2013. - №1. - S. 7-11
2. Hayrullin R.A. Reakcii alifaticheskih al'degidov s hloridami R(III). II. Sintez pervichnyh intermediatov v prisutstvii organicheskih azotistyh osnovaniy / R.A. Hayrullin, M.B. Gazizov, R.F. Karimova, T.N. Kachalova, R.R. Karimov // Vestnik KTU. - 2013. - №1. - S. 17-22
3. Hayrullin R.A. Reakciya alifaticheskih al'degidov s hloridami P(III). III. Sintez pervichnyh intermediatov v prisutstvii alkilvinilovyh efirov / R.A. Hayrullin, M.B. Gazizov, R.F. Karimova, T.N. Kachalova // Vestnik KTU. - 2013. - №1. - S. 26-30
4. Hayrullin R.A. Reakciya alifaticheskih al'degidov s hloridami P(III). IV. Vzaimodeystvie pervichnyh intermediatov, ne soderzhaschih aktivnogo atoma hlora u P(III), s aprotonnymi reagentami / R.A. Hayrullin, M. B. Gazizov, R.F. Karimova, N.N. Gazizova // Vestnik KTU. - 2013. - №4. - S. 38-42
5. Karimova R.F. Reakciya alifaticheskih al'degidov s hloridami P(III). V. Vzaimodeystvie pervichnyh intermediatov, soderzhaschih aktivnyy atom hlora u P(III), s aprotonnymi reagentami / R.F. Karimova, M.B. Gazizov, R.A. Hayrullin, K.S. Gazizova, A.Yu. Bandikova // Vestnik KTU. - 2013. - №4. - S. 45-49
6. Hayrullin R.A. Reakcii alifaticheskih al'degidov s hloridami P(III). VI. Vzaimodey-stvie pervichnyh intermediatov s okislitelyami / R.A. Hayrullin, M. B. Gazizov, R.F. Karimova, K.S. Gazizova, N.G. Aksenov // Vestnik KTU. - 2013. - №6. - S. 9-13
7. Karimova R.F. Reakcii alifaticheskih al'degidov s hloridami P(III). VII. Reakcii pervichnyh intermediatov s hloriruyuschimi reagentami / R.F. Karimova, M.B. Gazizov, R.A. Hayrullin, R.N. Burangulova, V.G. Nikitin // Vestnik KTU. - 2013. - №6. - S. 13-16
8. 8. Gazizov Mukattis B. New products of the reaction of aldimines with dialkylphosphites / Mukattis B. Gazizov, Rafail A. Khairullin, Anastasya I. Alehina, Igor A. Litvinov, Dmitrii B. Krivolapov, Shamil K. Latipov, Alsu A. Balandina, Rashid Z. Musin, Oleg G. Sinyashin // Mendeleev Commun. 2008.-V18.- P. 262-264
9. Gazizov M.B. Vzaimodeystvie dialkilfosforistyhkislot s N-alkil- 2-hloral'degidiminami / M.B. Gazizov, R.A. Hayrullin, A.A. Minnihanova, A.I. Alehina, A.A. Bashkircev, O.G. Sinyashin //Doklady RAN.-2012.-T.433, №3.-S.1-5
10. Gazizov Mukattis B. Phosphorylated aziridium salts: synthesis and ring opening with nucleophiles / Mukattis B. Gazizov, Pafail A. Khairullin, Alina A. Minnikhanova, Anastasya I. Alekhina, Rashid Z. Musin, Oleg G. Sinyashin // Mendeleev Commun. 2011.-V21.-P.1-3
11. Gazizov M.B. Reakcii dialkilfosforistyh kislot s N-alkil-2-hloral'diminami / M.B. Gazizov, R.A. Hayrullin, A.A. Minnihanova, A.I. Alehina, A.A. Bashkircev // Vestnik KTU.-2010, №5. S.55-59
12. Gazizov Mukattis B. Reaction of Dialkylphosphites with N-alkyl-2-chloroaldimines / M.B. Gazizov, R.A. Khairullin, A. A. Minnikhanova, A.I. Alehina, A.A. Bashkirtsev, O.G. Sinyashin // Russian Journal of General Chemistry. - 2012.-V. 80, №12.-R. 2425-2429
