This article gives an overview of known methods of modification of carbon fibers (CF). The many of basic principles of surface treatment fibrous materials were considered. Was analyzed the interactions of tools to influence the surface of fibers Found that one of promising methods of modification of the surface layers is the impact of radio-frequency capacitive plasma flow discharge of low pressure.
углеродное волокно, полимерный композиционный материал, межфазные свойства, адгезия, модификация, carbon fibers, composites, interfacial properties, adhesion, modification
1. ZAO "Holdingovaya kompaniya "Kompozit [Elektronnyy resurs]. - Rezhim dostupa: http: //www.hccomposite.com, svobodnyy.
2. Frolov Yu.G. Kurs kolloidnoy himii. Poverhnostnye yavleniya i dispersnye sistemy. Ucheb. dlya VUZov.2-e izd., pererab. i dop. - M.,1988. -464 s.
3. Mihaylin Yu.A. Konstrukcionnye polimernye kompozicionnye materialy., 2-e izdanie. M.: Izd-vo Nauchnye osnovy i tehnologii, 2008. - 822 s.
4. Tihomirov A.S. Modificirovanie poverhnosti uglerodnogo volokna rastvorami azotnoy kisloty / A.S.Tihomirov, N.E. Sorokina, V.V. Avdeev // Neorgan. mater. - 2011. 47. N 6, s. 684-688.
5. Li J. The effect of nitric acid oxidization treatment on the interface of carbon fiber-reinforced thermoplastic polystyrene composite / J. Li., F.F. Sun // Polym.-Plast. Technol. and Eng. - 2009. 48. N 7. P. 711-715.
6. Modification of the surfaces of a gas activated carbon and a chemically activated carbon with nitric acid, hypochlorite and ammonia / P. Vinke, Vander Eijk M., M. Verbree, A.F. Voskamp, Van Bekkum H. // Carbon. - 1994. - V.32. №4. - P.675-686.
7. Activated sarbon surface modifications by nitric acid, hydrogen peroxide and ammonium peroxydisulfate treatments / S. Moreno-Castilla, M.A. Ferro-Garcia, J.P.Joly, I.Bautista-Toledo, F.Carrasco-Marin, J.Rivera-Utrilla// Langmuir. - 1995. -V.11. №11. - P.4386-4392.
8. Chen S. Improvement of the Reduction Capacity of Activated Carbon Fiber / S. Chen, H. Zeng // Carbon. - 2003. - V.41. №6. - P.1265-1271.
9. Effect of fiber acid treatment on the dynamic mechanical properties of unsaturated polyester/carbon fiber unidirectional composites / F. Babak, E. Masoud, S. A. Khalifeh, A. I. Amiri // Polym.-Plast. Technol. and Eng. - 2011. 50. N 6. - P. 564-567.
10. Chemical modification of carbon fiber surfaces / F. Severini, L. Formaro, M. Pegoraro, L. Posca // Carbon. - 2002. V.40. N 5. - P. 735-741.
11. J.P. Boudou Surface chemistry of a viscose-based activated carbon cloth modified by treatment with ammonia and steam // Carbon. -2003. V. 41. P. 1955-1963
12. Influence of high temperature and pressure ammonia solution treatment on interfacial behavior of carbon fiber/epoxy resin composites/ L.H. Meng, Z.W. Chen, X.L. Song, Y.X. Liang, Y.D. Huang, Z.X. Jiang // J. Appl. Polym. Sci. 2009. 113, N 6. - p. 3436-3441.
13. Harry I.D. Surface properties of electrochemically oxidised viscose rayon based carbon fibres / I.D. Harry, V. Saha, I.W. Cumming, // Carbon. 2007. V.45. - P.766-774.
14. Pat. 2052549 RF, MPK6D 01 F 11/10. Sposob modifikacii poverhnosti uglevoloknistyh materialov / I.L. Kumok, M.V.Tihomirova; NPO «Himvolokno». -№ 5062043/05; zayavl. 10.09.1992; opubl. 20.01.1996.
15. Pat. 2080427 RF, MPK6D 01F11/16. Sposob poverhnostnoy obrabotki voloknistyh materialov na osnove uglerodnogo volokna / V.M. Bondarenko [i dr.]. 94020979/04; zayavl. 06.06.1994; opubl. 27.05.1997.
16. Elektrohimicheskaya modifikaciya poverhnostnyh svoystv uglerodnogo volokna na osnove poliakrilonitrila / I.S. Strahov, A.A. Gubanov, M.S. Ustinova, D.I. Krivcov, V.Ya. Varshavskiy, T.A. Vagramyan, I.V. Plyuschiy, Yu.V. Korshak // Nauka i Obrazovanie. 2013. №9. - s. 29-42.
17. Anodization of carbon fibers on interfacial mechanical properties of epoxy matrix composites / S.-J. Park, Y.-H. Chang, Y.-C. Kim, K.-Y. Rhee // J. Nanosci. and Nanotechnol. 2010. 10. N 1. - P. 117-121.
18. Guo Yun-xia. Xinxing tan cailiao / Guo Yun-xia, Liu Jie, Liang Jie-ying //New Carbon Mater. 2006. 21, N 4, s. 343-348. Kit.; rez. angl.
19. The mechanical and tribological properties of anodic oxidation treatment carbon fiber-filled PU composite / Zang Zhaoliang, Tang Gang, Wei Gaofeng, Wang Dongmei, Chang Daofang, Huang Jiahui, Yan Wei // Polym.-Plast. Technol. and Eng. 2012. 51, N 15, p. 1501-1504.
20. Megerdigian C. 33 Int. SAMPE Symposium, march 7-10, 1988, p. 571-582.
21. Vautard F. Properties of thermo-chemically surface treated carbon fibers and of their epoxy and vinyl ester composites / F. Vautard, S. Ozcan, H. Meyer // Composites. A. 2012. 43, N 7. - P. 1120-1133.
22. Vautard F. Influence of an oxidation of the carbon fiber surface on the adhesion strength in carbon fiber-acrylate composites cured by electron beam./ F. Vautard, P. Fioux, L. Vidal, J. Schultz, M. Nardin, B. Defoort // Int. J. Adhes. and Adhes. 2012. 34. - P. 93-106.
23. Vautard F. Influence of thermal history on the mechanical properties of carbon fiber-acrylate composites cured by electron beam and thermal processes/ F. Vautard, S. Ozcan, L. Poland, M. Nardin, H. Meyer // Composites. A. 2013. 45. P. 162-172.
24. Golovina E.A. Osnovy radiacionnogo materialovedeniya/ E.A. Golovina, V.B. Markin // Uchebnoe posobie. - Barnaul: Izd-vo AltGTU, 2008. - 145 s.
25. Hengyi Ma, Yudong Huang, Zhiqian Zhang. Treatment of carbon fiber by gamma-ray irradiationg to improvement of interfacial adhesion in epoxy resin composites. 4-aya Mezhdunarodnoy nauchno-tehnicheskoy konferencii "Kompozity - v narodnoe hozyaystvo Rossii" ("Kompozit-02"). Barnaul: Izd-vo AltGTU. 2002, s. 31-37.
26. Zhao Feng, Huang Yudong. Modifikaciya uglerodnogo volokna metodom radiacionnoy privivki. Uniform modification of carbon fibers in high density fabric by γ-ray irradiation grafting // Mater. Lett. 2011. 65, N 23-24. - P. 3351-3353.
27. Abu Bakar M. A., Ahmad S. Kuntjoro W. Effect of gamma radiation surface treatment to the mechanical properties of short carbon fibre reinforced epoxy composites // Canadian Journal on Scientific and Industrial Research. 2010. Vol. 1, No. 3.
28. Effect of γ-ray irradiation grafting on the carbon fibers and interfacial adhesion of epoxy composites/ Xu Zhiwei, Huang Yudong, Zhang Chunhua, Liu Li, Zhang Yanhua, Wang Lei // Compos. Sci. and Technol. 2007. 67, N 15-16. - P. 3261-3270. Angl.
29. Tiwari S., Bijwe J., Panier S. Gamma radiation treatment of carbon fabric to improve the fiber-matrix adhesion and tribo-performance of composites//Wear. 2011. 271, N 9-10. - P. 2184-2192.
30. Atmospheric plasma treatment of carbon fibers for enhancement of their adhesion properties/ Santos, A.L., Botelho, E.C., Kostov, K.G., Nascente, P.A.P., Da Silva, L.L.G. // IEEE Transactions on Plasma Science,2013 ,(2), art. no. 6412809. - P. 319-324.
31. A study of the effect of nitrogen and air plasma immersion ion implantation treatments on the properties of carbon fiber/ Da Silva, L.L.G., Alves, L.G., Tóth, A., Ueda, M. // IEEE Transactions on Plasma Science, 2011, 39 (11 PART 2), art. no. 5960797. - P. 3067-3071.
32. Improving carbon fiber adhesion to polyimide with atmospheric pressure plasma treatment / Xie Jianfei, Xin Danwei, Cao Hongyan, Wang Cuntao, Zhao Yi, Yao Lan, Ji Feng, Qiu Yiping // Surface and Coat. Technol. 2011. 206, N 2-3. - P. 191-201.
33. Effect of atmospheric plasma treatment of carbon fibers on crack resistance of carbon fibers-reinforced epoxy composites/ S.-J. Park, J.-S. Oh, K.-Y. Rhee // Carbon Science. 2005. V. 6, No. 2. - P. 106-110.
34. Effect of using oxygen, carbon dioxide, and carbon monoxide as active gases in the atmospheric plasma treatment of fiber-reinforced polycyanurate composites / R. J. Zaldivar, J. P. Nokes, D. N. Patel, B. A. Morgan, G. Steckel, H. I. Kim// Journal of Applied Polymer Science. 2012. V. 125. P. - 2510-2520.
35. Surface preparation for adhesive bonding of polycyanurate-based fiber-reinforced composites using atmospheric plasma treatment/ R. J. Zaldivar, H. I. Kim, G. L. Steckel, D. Patel, B. A. Morgan, J. P. Nokes // Journal of Applied Polymer Science. 2011. V. 120. - P. 921-931.
36. T. S. Williams. PhD Chemical Engineering. UCLA. Los Angeles 2013. P.267.
37. Anan'eva E.S. Vliyanie plazmohimicheskoy modifikacii poverhnosti uglerodnyh volokon na mehanizm razrusheniya ugleplastikov / E.S. Anan'eva, S.V.Anan'ev // Vestnik TGU. -2010. - T.15, vyp.3. - S.1007-1009.
38. A study of the effect of oxygen plasma treatment on the interfacial properties of carbon fiber/epoxy composites/Keming Ma, Ping Chen, Baichen Wang, Guiling Cui, Xinmeng Xu // Journal of Applied Polymer Science. 2010. V. 118. P. - 1606-1614.
39. Effect of oxygen plasma-treated carbon fibers on the tribological behavior of oil-absorbed carbon/epoxy woven composites / K. Y. Rhee, S.J. Park, D. Hui, Y. Qiu.//Composites. B. 2012. 43, N 5, s. 2395-2399.
40. Zhongguo biaomian gongcheng/ Zhu Nai-shu, Ma Shi-ning, Sun Xiao-feng, Chen Xi. // China Surface Eng. 2010. 23. N 5. - P. 59-63. Bibl. 14. Kit.; rez. angl.
41. Nie W. Z., Li J. Effects of plasma and nitric acid treatment of carbon fibers on the mechanical properties of thermoplastic polymer composites // Mech. Compos. Mater. 2010. 46. N 3. - P. 251-256.
42. V.A. Petyaev.; Nac. issled. centr "Kurchatovskiy institut" - Moskva, 2013 - 22 s.
43. Tao C. Chang. Plasma Surface Treatment In Composites Manufacturing // Ind.Technology. V. 15, N. 1. - 1999.
44. Shelestova V.A. Plazmohimicheskoe nanesenie ftorpolimernyh pokrytiy na uglerodnye volokna/V.A. Shelestova, V.V. Serafimovich, P.N. Grakovich // Materialy IV Mezhdunarodnogo simpoziuma po teoreticheskoy i prikladnoy plazmohimii. Ivanovo - 2014.
45. Sergeeva E.A. Izmenenie poverhnostnyh i fiziko-mehanicheskih svoystv aramidnyh volokon, modificirovannyh potokom plazmy vysokochastotnogo emkostnogo razryada ponizhennogo davleniya / E.A. Sergeeva, A.R. Ibatullina // Vestnik Kazanskogo tehnologicheskogo universiteta. 2012. №4. - S. 63-66.
46. Sergeeva E.A. Gidrofilizaciya poverhnosti tkaney na osnove volokon iz sverhvysokomolekulyarnogo polietilena s pomosch'yu plazmennoy obrabotki / E.A. Sergeeva, Yu.A. Bukina, I.P. Ershov // Vestnik Kazanskogo tehnologicheskogo universiteta. 2012. t.15. № 17. - S.110 -112.
47. Sergeeva E.A. Prochnostnye harakteristiki kompozicionnyh materialov na osnove plazmoaktivirovannyh sverhvysokomolekulyarnyh polietilenovyh volokon/Sergeeva E.A., Ibatullina A.R., Brysaev A.S. // Vestnik Kazanskogo tehnologicheskogo universiteta. 2012. t.15, №18. - S. 133-136.