A bis-diphosphine nickel complexes with pendant amines [Ni(P R’ 2N R 2) 2](BF 4) 2 has been tested in polymer electrolyte membrane fuel cells. A membrane electrode assembly was made as a sandwich of [Ni(P R’ 2N R 2) 2] 2+/Vulcan XC-72 + Nafion ionomer-coated anode, a Nafion 212 membrane, and [Ni(P R’ 2N R 2) 2] 2+/Vulcan XC-72 + Nafion ionomer-coated cathode.
водородная энергетики, катализатор, топливные элементы, окисление водорода, hydrogen economy, molecular catalysis, fuel cells, hydrogen reduction, fullerene
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