The influence of formic and benzoic acids in the synthesis of molybdenum catalyst epoxidation of olefins. It is shown that benzoic acid completely suppresses interaction of metal molybdenum with hydroperoxide ethylbenzene in ethanol. Formic acid has no effect in the process of preparation of the catalyst, but reduces conversion ethylbenzene hydroperoxide in epoxidation reactions.
молибден, катализатор, муравьиная кислота, бензойная кислота, гидропероксид этилбензола, эпоксидирование, molybdenum, catalyst, formic acids, benzoic acids, epoxidaition, hydroperoxide, propylene, solubility
1. Smolin R.A. Gidroperoksidnoe epoksidirovanie model'nogo oktena-1 v prisutstvii molibdenovoy sini / R.A. Smolin, N.N. Batyrshin, G.G. Elimanova, H.E. Harlampidi // Vestnik Kazanskogo tehnologichsekogo universiteta - 2011.- № 18. - S.38-43.
2. Serebryakov, B.R. Novye processy organicheskogo sinteza / B.R. Serebryakov, R.M. Masagutov, V.G. Pravdin. - M.: Himiya, 1989. - 400 s
3. Karpenko L.P. Sintez katalizatora epoksidirovaniya na osnove metallicheskogo molibdena / Karpenko L.P., Serebryakov B.R., Galanterik R.E., Konoval'chukov A.G., Kacharov V.G. // ZhPH. - 1975. - Vyp.8. - s.1706-1709.
4. Busev A.I. Analiticheskaya himiya molibdena. - M.: AN SSSR. 1962. 306 s.
5. Antonovskiy V.L. Iodometricheskoe opredelenie koncentracii gidroperoksidov // Analiticheskaya himiya organicheskih peroksidnyh soedineniy/ Antonovskiy V.L., Buzlanova M.M. // - M.:Himiya,1978. - S.20-22.
6. Godovskaya K.I. Opredelenie soderzhaniya epoksigrupp v epoksidnyh smolah / K.I. Godovskaya, Ryabinina L.V // Tehnicheskiy analiz.-M.: Vysshaya shkola, 1972. - S.420-425.