Cumene hydroperoxide decomposition in chlorobenzene in the presence of calcium 2-ethylhexanoate and naphthenate was investigated. It was established and kinetically proved that the decomposition reaction is preceded by the formation of a hydroperoxide-catalyst complex. It was found, that the ligand surrounding of Calcium ion has impact on composition products decomposition of hydroperoxide.
гидропероксид кумола, 2-этилгексаноат кальция, нафтенат кальция, каталитическое разложение, cumene hydroperoxide, calcium 2-ethylhexanoate, calcium naphthenate, catalytic decomposition
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