The titanylsulphate - dl-tartaric acid system was studied by the methods of pH-metric titration and mathematical simulation in a wide pH range for the 1:1- 1:3 ratios of metal-to-ligand. The stoichiometry and formation constants of the complex forms were calculated. The formation of polynuclear species including dimers and tetramers has been found along with mononuclear species.
dl-тартраты титана(IV), комплексообразование в растворах, потенциометрическое титрование, математическое моделирование, titanium(IV) dl- tartrates, complex formation in solutions, pH-metric titration, mathematical simulation
1. R. Uppal, C. Incarvito, K. Lakshmi, A. Valentine, Inorg. Chem., 45, 4, 1795-1804 (2006)
2. K. Buettner, J. Collins, A. Valentine, Inorg. Chem, 51, 20, 11030−11039 (2012)
3. K. Buettner, A. Valentine, Chem. Rev, 112, 3, 1863-1881 (2012)
4. M. Kakihana, K. Tomita, V. Petrykin, M. Tada, S. Sasaki, Y. Nakamura, Inorg. Chem, 43, 15, 4546−4548 (2004)
5. Y.-F. Deng, Y.-Q. Jiang, Q.-M. Hong, Z.-H. Zhou, Polyhedron, 26, 8, 1561-1569 (2007)
6. P. Panagiotidis, E.T. Kefalas, C.P. Raptopoulou, A. Terzis, T. Mavromoustakos, A. Salifoglou, Inorganica Chimica Acta, 361, 8, 2210-2224 (2008)
7. E. Kefalas, P. Panagiotidis, C. Raptopoulou, A. Terzic, T. Mavromoustakos, A. Salifoglou, Inorg. Chem, 44, 8, 2596-2605 (2005)
8. Y.-F. Deng, Z.-H. Zhou, H.-L. Wan, Inorg. Chem, 43, 20, 6266-6273 (2004)
9. Z.-H. Zhou, Y.-F. Deng, T.-Q. Jiang, H.-L. Wan, S.-W. Ng. J. Chem. Soc, Dalton Trans., 13, P.2636-2638 (2003)
10. M. Dakanali, E.T. Kefalas, C.P. Raptopoulou, A. Terzis, G. Voyiatzis, I. Kyrikou, T. Mavromoustakos, A. Salifoglou, Inorg. Chem, 42, 15, 4632-4639 (2003)
11. M. Kakihana, M. Tada, M. Shiro, V. Petrykin, M. Osada, Y. Nakamura, Inorg. Chem, 40, 5, 891-894 (2001)
12. T. Kemmitt, N.I. Al-Salim, G.J. Gainsford, A. Bubendorfer, M. Waterland. Inorg. Chem, 43, 20, 6300-6306 (2004)
13. J. Paradies, J. Crudass, F. MacKay, L. Yellowlees, J. Montgomery, S. Parsons, I. Oswald, N. Robertson, P. Sadler. J. Inorg. Biochem, 100, 7, 1260-1264 (2006)
14. B. Zumreoglu-Karan. Coord. Chem. Rev, 250. 17-18, 2295-2307 (2006)
15. S.G. Bezryadin, V.V. Chevela, O.P. Aysuvakova, V.Yu. Ivanova, Butlerovskie soobscheniya, 35, 8, 59-66 (2013)
16. S.G. Bezryadin, V.V. Chevela, O.P. Aysuvakova, V.Yu. Ivanova, Butlerovskie soobscheniya, 35, 8, 67-73 (2013)
17. K. Sharpless, S. Woodard, M. Finn, Pure & Appi. Chem, 55, 11, 1823-1836 (1983)
18. C. Wensheng, H. Ronghua, European polymer journal, 37, 8, 1553-1559 (2001)
19. H. Shi, C. Yu, J. He, J. Phys. Chem C, 114, 41, 17819-17828 (2010)
20. H. Shi, C. Yu, J. He, Journal of Catalysis, 271, 12, 79-87 (2010)
21. A.I. Busev, V.G. Tipcova, V.M. Ivanov, Rukovodstvo po analiticheskoy himii redkih elementov. Himiya, Leningrad, 1978. 432 s.
22. H. Hattori, M. Hoshino, T. Wakii, A. Yuchi, Anal. Chem, 76, 17, 5056-5062 (2004)
23. I.V. Pyatnickiy, V.V. Suhan, Maskirovanie i demaskirovanie v analiticheskoy himii. Nauka, Moskva, 1990. 222 s.
24. V.V.Chevela, S.G. Bezryadin, V.Yu. Ivanova, L.I. Muhamed'yarova, N.A. Grigor'eva, V.S. Zalymov, L.G.Smirnova, Uchen. zap. Kazan. un-ta. Ser. Estestv. nauki, 152, 4, 249-254 (2010)
25. F. Kadyrov, S. Bahteev, R. Yusupov, M. Shaehov, Vestnik Kazanskogo tehnologicheskogo universiteta, 16, 5, 148-149 (2013)
26. V.V. Biktagirov, Vestnik Kazanskogo tehnologicheskogo universiteta, 1, S. 29-34 (2007)
27. P. Erlih, H. Kyunl', V sb. Rukovodstvo po neorganicheskomu sintezu. T.4. Mir, Moskva, 1985. S. 1469-1470
28. V.A. Nazarenko, V.P. Antonovich, E.M. Nevskaya, Gidroliz ionov metallov v razbavlennyh rastvorah. Atomizdat, Moskva, 1979. 192 s.
29. S.V. Elinson, K.I. Petrov, Analiticheskaya himiya cirkoniya i gafniya. Nauka, Moskva, 1965. 241 s.
30. Yu.Yu. Lur'e, Spravochnik po analiticheskoy himii. Himiya, Moskva, 1989. 448 s.
31. Yu.I. Sal'nikov, A.N. Glebov, F.V. Devyatov, Poliyadernye kompleksy v rastvorah. Izd. Kazanskogo un-ta, Kazan', 1989. 288 s.
32. A. Al'bert, E. Serzhant, Konstanty ionizacii kislot i osnovaniy. Himiya, Moskva, 1964, 179 s.
33. L. Ciavatta, D. Ferri, G. Ricco, Polihedron, 4, 1, 15-21 (1985)
34. K.G. Knauss, M.J. Dibley, W.L. Bourcier, Appl. Geochem, 16, 9-10, 1115-1128 (2001)
35. V.P. Vasil'ev, P.N. Vorob'ev, I.L. Hodakovskiy. Zh. Neorg. Himii, 19, 10, 2712-2716 (1974)
36. C.F. Baes, R.E. Mesmer, The Hydrolysis of Cations; John Wiley &Sons: New York, 1976. 489 p.
37. H. Einaga, Y. Komatsu, J. Inorg. Nucl. Chem., 43, 10, 2443-2448 (1981)
38. 38. V.V. Chevela, S.G. Bezryadin, S.N. Matveev, V.E. Semenov, G.A. Shamov, N.B. Berezin, L.G. Smirnova, V.Yu. Ivanova, Struktura poliyadernyh d- i dl-tartratov lantanoidov v vodnom rastvore, Izd. Centr. OGAU, Orenburg. 180 s.
