The optical, thermal and mechanical properties of a commercial pearlescent and multilayer BOPP film were determined in the present study. The film was polypropylene and it was biaxially oriented. Thermal gravimetric analysis indicated 11.2 % of calcite in the film. The film thermally degraded in two steps. The first and the second steps were for the polymer fraction and decomposition of calcite respectively. For 10 oC/min heating rate the onset of polypropylene degradation was 250 oC and calcite decomposition was 670 oC. The activation energies for polypropylene degradation and calcite decomposition were 64.8 kJ/mol and 204.8 kJ/mol. The tensile strength of the film in machine and transverse directions were 97.7 and 35.9 MPa respectively.
pearlescent film, BOPP, calcite, tensile strength, thermal gravimetric analysis, перламутровая пленка, БОПП, кальцит, прочность при растяжении, термогравиметрический анализ
1. Introduction of BOPP Film http://decrobopp.wordpress.com (2013)
2. Ulku S., Balkose D., Arkis E.,Sipahioglu, M., A study of chemical and physical changes during biaxially oriented polypropylene film production, Journal of Polymer Engineering, 2003, 23, 437-456
3. Kalapat N. and Amornsakchai T., Surface modification of biaxially oriented poly-propylene (BOPP) film using acrylic acid-corona treatment: Part I. Properties and characterization of treated films, Surface and Coating Technology,2012, 207, 594-601
4. Nie H.Y, Walzak M. J., McIntyre N. S., Atomic force Microscope Study of Biaxially Oriented Films, Journal of Materials Engineering and Performance,2009, 13 (4) 4511-460
5. http://www.tainstruments.co.jp/application/pdf/Thermal_Library/Applications_Briefs/TA125.PDF
6. http://perlas.com.mx/en/quality/luster.html,2014
7. Birley A.W., Haworth B., Batchelor J., Physics of Plastics: Processing Properties And Materials Engineering, Hanser Publishers, Munich (1992)
8. Lin Y.J., Dias P., Chum S., Hiltner A., Baer E., Surface roughness and light transmission of biaxially oriented polypropylene films, Polymer Engineering and Science, 2007,47, 1658-1665
9. Yuksekkalayci C., Yilmazer U., Orbey N., Effects of Nucleating Agent and Processing Conditions on the Mechanical, Thermal and Optical Properties of Biaxially Oriented Polypropylene Films, Polymer Engineering and Science, 1999, 39,1216-1222