MODIFICATION OF POLYAMIDE- 6 BY N, N'- BIS - MALEAMIDOACID
Abstract and keywords
Abstract (English):
Article is devoted to receiving and research of compositions on the basis of industrially made polyamide-6 modified by N,N '-bis-maleamidoacid of metaphenylenediamine. Existence in macromolecules of polyamides reactive carboxyl, amide and amino groups, capable to interact with multifunctional monomeric and oligomeric modifiers, gives the chance of receiving the materials possessing properties of sewed polymers. As a result the use of bis-amidoacid as a modifying additive in the system of aliphatic polyamide-6 provides the improvement of strength properties and thermal characteristics of a polymeric material.

Keywords:
N,N'- diphenylmethane-bis-maleinimide, N,N'- diphenyloxide - bis-maleinimide, N,N'- m-phenylene-bis-maleinimide, мodification, еnergy activation, Polyamid-6, полиамид-6, N, N'-дифенилметандиизоцианата-бис-малеимид, N, N 'дифенилоксида - бис-малеимид, N, N'-м-фенилен-бис-малеимид, модификация, энергия активации
References

1. G.I. Kudryavtsev, M.P. Noskov, A.V. Volokhina / Polyamide fibers. - M.: "Chemistry". - 1976. - 259 p.

2. G. Hapugalle, N.R. Prokopchuk, V.P. Prakapovich, I.A. Klimovtsova/New thermostabilizers polyamide -6 / / NASB Vestsі. Ser.hіm.navuk. - 1999. - № 1, p.114-119.

3. The anionic polymerization of ε-caprolactam and its copolymerization with ω-dodekalaktamom in the presence of aromatic polyimides / Y.S. Vygodskii [etc.] / Polym. comp. Ser. A. - 2006. - V. 48, № 6. - P. 885-891.

4. The anionic polymerization of ε-karolaktama in the presence of aromatic polyimides as macromolecular activators / YS Vygodskii [etc.] / Polym. comp. Ser. A. - 2003. - T. 45, № 2. - P. 188-195.

5. The anionic polymerization of ε-caprolactam in the presence of aromatic diimides / Y.S. Vygodskii [etc.] / Polym. comp. Ser. A. - 2005. - Volume 47, № 7. - P. 1077.

6. About modifying the action of N, N'-bis-imides of unsaturated dicarboxylic acids, aliphatic polyamides / V. Biran [etc.] / / Reports of the Academy of Sciences of the Byelorussian SSR. - 1983. - V. 27, № 8. - P. 717-719

7. Synthesis of N, N'-bis-imides of unsaturated dicarboxylic acids, cycloaliphatic / A.I. Volozhin [etc.] / / Vestsі BSSR. Ser. hіm. Navuka. - 1974. - № 1. - P. 98-100.

8. Nakanishi, K. Infrared spectra and structure of organic compounds / K. Nishi Naka. - New York: Wiley, 1965. - P. 216.

9. The study by EPR of free radicals in polyimides / A.G. Boldyrev [etc.] / / Report of the Academy of Sciences of the USSR. - 1965. - T. 163, № 5. - P. 1143-1146.

10. Ingram, D. Electron Paramagnetic Resonance in Biology / D. Ingram; under Society. Ed. Y.I. Agip, L.P. Kayushin. - New York: Wiley, 1972. - P. 296.

11. Broido A., Semple A. Sensitive graphical method of treating thermogravimetric analysis date // I. Polym. Sci. - 1969. - Part A. 2. - v. 7. - № 10. - R. 1761-1773.

12. Prokopchuk N.R. study the thermal stability of polymers by derivatography // Vestsі BSSR. Ser. hіm. Navuka. -1984. - № 4. - P. 119 -121.

13. Polymer construction. Method for determining the durability of the activation energy for thermal oxidative degradation of polymeric materials: STB 13330-2002. - Enter. 28.06.2002. - Minsk: Technical Committee on technical regulation and standardization in construction: the Ministry of Architecture and Construction of Belarus, 2002. - 8 p.

Login or Create
* Forgot password?