Polymerization of the modified butylmethacrylate fraction of liquid pyrolysis products (C9, dicyclopentadiene, cyclopentadiene) under the influence of titanium tetrachloride was investigated thermometric method. As a result, oligomeric products containing butyl methacrylate units were produced. It was established that the first step of the process is the formation of titanium tetrachloride - butylmethacrylate complex. This complex is capable of initiating the polymerization of unsaturated compounds fraction of liquid pyrolysis products.
полимеризация, жидкие продукты пиролиза, бутилметакрилат, тетрахлорид титана, polymerization, liquid pyrolysis products, butylmethacrylate, titanium tetrachloride
1. K.V. Ermizin, V.G. Bondaletov, A.A. Lyapkov, L.I. Bondaletova, A.A. Troyan, E.I. Ionova, A.A. Manankova, V.N. Manzhay, Him. promyshlennost', 86, 6, 35-44 (2009).
2. A.D. Berenc, V.A. Men'shikov, Him. promyshlennost', 5, 19-23 (1993).
3. Yu.V. Dumskiy, B.I. No, G.M. Butov, Himiya i tehnologiya neftepolimernyh smol. Himiya, Moskva, 1999. 312 s.
4. V.G. Bondaletov, S.I. Prihod'ko, I.G. Antonov, K.V. Ermizin, N.N. Kuznecov, E.P. Fiterer, Plasticheskie massy, 5, 48-50 (2004).
5. M.J. Zohuriaan-Mehr, H. Omidian, J.M.S. - Rev. Macromol. Chem. Phys, C 40, 1, 23-49 (2000).
6. A.A. Lyapkov, V.G. Bondaletov, L.I. Bondaletova, E.I. Ionova, E.P. Fiterer, A.V. Evdokimov, Neftepererabotka i neftehimiya, 12, 36-39 (2007).
7. E.N. Harlamova, E.N. Gur'yanova, N.A. Slovohotova, Zhurnal obschey himii, 37, 303-307 (1967).
8. O.V. Bondaletov, L.I. Bondaletova, V.G. Bondaletov, V.V. Bochkarev, V sb. Fiziko-himiya polimerov: Sintez, svoystva i primenenie. Vyp. 17. Tver. gos. un-t, Tver', 2011. S. 254-258.
9. O.V. Bondaletov, V.G. Bondaletov, L.I. Bondaletova, V.V. Bochkarev, Izvestiya TPU, 318, 3, 92-96 (2011).
10. V.G. Bondaletov, O.V. Bondaletov, L.I. Bondaletova, M.E. Tavanova, V sb. Fiziko-himiya polimerov: Sintez, svoystva i primenenie. Vyp. 18. Tver. gos. un-t, Tver', 2011. S. 248-353.
