We consider the process terpolimerization of major unsaturated components of liquid products of gasoline pyrolysis in toluene as a model for the oligomerization of C 9 fraction under the action of the catalytic system TiCl 4 - Et 2AlCl. It was established the relative reactivity of styrene, indene, and dicyclopentadiene comprising 80...85 % of the total quantity of monomers in fraction. On the basis of the adiabatic temperature thermometry, as well as IR and 1H NMR spectroscopy, the possibility of obtaining poly(oligo)-dimensional products, mostly industry-petroleum polymer resins derived from the C 9 fraction.
каталитическая олигомеризация, терполимеризация, жидкие продукты пиролиза, нефтеполимерные смолы, дициклопентадиен, стирол, a-метилстирол, винилтолуол, инден, фракция С 9, тетрахлорид титана, адиабатическая установка, термометрический метод, константы скорости, моделирование, catalytic oligomerization, terpolymerization, liquid products of pyrolysis, petroleum resins, dicyclopentadiene, styrene, a-methylstyrene, vinyltoluene, indene, C 9 fraction, titanium tetrachloride, an adiabatic reactor, the thermometric method, the rate constant, modeling
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