New approach was developed to the investigation of the reactions of aliphatic aldehydes with the electrophilic P(III) chlorides. Its essence is the removal of HCl admixture from P(III) chloride, activation of aldehyde molecule and block out the electrophilic center of carbonyl group by the organic nitrogen bases and alkyl vinyl ethers.
альдегиды, хлориды P(III), примесь HCl, электрофильный центр, каталитическое блокирование, органические основания, алкилвиниловые эфиры, aldehydes, P(III) chlorides, HCl admixture, electrophilic center, block-out, organic nitrogen bases, alkyl vinyl ethers
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