Allyl radicals have been generated in the main chain at the base of the side chain of perfluorinated membranes. Satellite lines of the quartet EPR spectra of membrane systems/water are forming due to the dipole-dipole interaction of the allyl radical with matrix protons of water molecules forming hydrogen bonds with the bridging oxygen at the bottom of the side chain and fluorine atoms of the main chain and become quite inactive. Structural and morphological parameters have been obtained from the analysis of the EPR spectra.
перфторированные мембраны, аллильные радикалы, матричные протоны, водородная связь, диполь-дипольное взаимодействие, спектры ЭПР, сателлитные линии, структурно-морфологические параметры, perfluorinated membranes, allyl radicals, matrix protons, hydrogen bonding, dipole-dipole interaction, EPR spectra, satellite lines, structural and morphological parameters
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