![KOMPLEKSNYE SOEDINENIYa GIDROKSIPROIZVODNOGO DINITROBENZOFUROKSANA. ChAST' 2. VZAIMODEYSTVIE TRIHLORIDA RODIYa S DINATRIEVYM KOMPLEKSOM 4,6-DINITRO-1-OKSOBENZ[6,5-C]-2,1,3-OKSADIAZOLDIOLA-5,7 V VODNOY SREDE](/upload/21232f297a57a5a743894a0e4a801fc3/journals/cover/95166a87c76a31158ddbba941da1ca51.jpeg)
To clarify the composition and structure of rhodium complex synthesized in aqueous medium under the interaction of rhodium trichloride and disodium complex of 4,6-dinitro-1-oksobenz[6,5-c]-2,1,3-oksadiazoldiol-5,7, mass spectrometry and 13 C NMR methods were applied. Determination of the main directions of decomplexation, composition and structure of the fragment ions, allows us to draw conclusion that the product is a polynuclear coordination compound of polyligand type with a layered structure included Rh( III ) and Rh( II ) ions. 13 C NMR data confirmed the nature of the coordination of the ligand to rhodium ions in the complex through a variety of functional groups, and established an interaction with π -electron system of heterocycles. According to X-ray analysis an isolated product has its own crystal lattice and exists as an individual compound. Virtual screening of biological activity indicates prospectively of experimental work for determining the biological activity of the compound.
гидроксипроизводные динитробензофураксана, динатриевый комплекс 4,6-динитро-1-оксобенз[6,5-c]-2,1,3-оксадиазолдиола-5,7, трихлорид родия, комплексообразование, синтез, водная среда, фрагментация, dinitrobenzofuroxane hydroxyderivatives, disodium 4,6-dinitro-1-oxobenz[6,5-c]-2,1,3-oxadiazoldiole-5,7 complex, rhodium trichloride, complexing, synthesis, aqueous medium, fragmentation
1. I. Blyum, Izvestiya Akademii Nauk. Seriya himicheskaya, 10, 1697-1705 (1993).
2. E.I. Gazizova. Diss. kand. him. nauk, Kazanskiy gosudarstvennyy tehnologicheskiy universitet, Kazan', 2008. 131s.
3. R. Sil'versteyn, G. Bassler, T. Morril, Spektrometricheskaya identifikaciya organicheskih soedineniy. Mir, Moskva, 1977. 590s.
4. X. Gyunter, Vvedenie v kurs spektroskopii YaMR. Mir, Moskva, 1984.462s.
5. L.A. Kazicina, N.B. Kupletskaya, Primenenie UF-, IK- i YaMR-spektroskopii v organicheskoy himii. Mir, Vyssh. Shkola, 1971. 264s.
6. E.V. Guseva i dr. // Vestnik Kazan. tehnol.un-ta, 12, 26-29 (2012)
7. L.M. Sven, F. Eva, G. Frank, M. Jens, L. Bemhard, Inorganic Chemistry, 37, 3195-3203 (1998).
8. V.C Jyothi Bhasu, M. Munavar Chaudri, J. Housden, J. Matrials Science, 26, 2199-2207 (1991).
9. Takakis Ioannis M., Tsantali George G., Haas George W., Giblin Daryl, L. Michael, J. Mass Spectrom., 34, 1137-1153 (1999).
10. I.V. Galkina i dr. Neobychnaya reakciya fosforilirovaniya dihlordinitrobenzofuroksana trifenilfosfinom // Tez. dokl. XVIII Mendeleev. s'ezda po obschey i prikladnoy himii. - M., 2007. - T. 1. - S. 168.
11. G.A. Kuznecova, Kachestvennyy rentgenofazovyy analiz: metodicheskie ukazaniya [Elektronnyy resurs]. - Rezhim dostupa: http://www.fineprint.com, svobodnyy.
12. T.A. Gloriozova, D.A. Filimonov, A.A. Lagunin, V.V. Poroykov, Him.-farm. zhurnal, 32, 12, 33-39 (1998).
13. A.V. Sadym, A.A. Lagunin, D.A. Filimonov, V.V. Poroykov Him.-farm. zhurnal, 36, 10, 21-26 (2002).
14. E.I. Gazizova, L.M. Yusupova, O.N. Kataeva, Vestnik Kazan. tehnol. un-ta, 6, 31-36 (2007).
