![KOMLEKSNYE SOEDINENIYa GIDROKSIPROIZVODNOGO DINITROBENZOFUROKSANA. ChAST' 3. VZAIMODEYSTVIE TRIHLORIDA RODIYa S DINATRIEVYM KOMPLEKSOM 4,6-DINITRO-1-OKSOBENZ[6,5-C]-2,1,3-OKSADIAZOLDIOLA-5,7 V VODNO-ACETONOVOY SREDE](/upload/21232f297a57a5a743894a0e4a801fc3/journals/cover/95166a87c76a31158ddbba941da1ca51.jpeg)
To clarify the composition and structure of rhodium complex synthesized in aqueous -acetone medium under the interaction of rhodium trichloride and disodium 4,6-dinitro-1-oxobenzo[6,5-c]-2,1,3-oxodiazoldiol-5,7 complex, mass spectrometry and 13 C NMR methods were applied can conclude that a structural unit consisting of compounds are distinguished [Rh 4 +3(C 6N 4O 8) 4 С l 16] , where the atom by furoxane cycle and N 3 = O group at C 6 carbon atom coordinating rhodium is ligand. The layers are binded by complex of rhodium( III ). In turn, in [Rh 4 +3(C 6N 4O 8) 4 С l 16] cations and rhodium cations surrounded viewed rhodium octahedral environment of the molecule which are water and chloride ions, whereby they are integrated in the chain. And so the octahedral environment of rhodium cations are molecules dioxidinitrobenzofuroxane, water and chloride ions. Connecting of cations by means of rhodium complex compound forms a cross-linked multilayer structure. The method of powder diffraction confirms identity of them. Virtual screening of biological activity showed marked immuno-stimulation properties in the treatment of system lupus erythematosus .
гидроксипроизводные динитробензофураксана, динатриевый комплекс 4,6-динитро-1-оксобенз[6,5-c]-2,1,3-оксадиазолдиола-5,7, трихлорид родия, комплексообразование, синтез, водно-ацетоновая среда, фрагментация, dinitrobenzofuroxane hydroxyderivatives, disodium 4,6-dinitroо-1-oxobenz[6,5-c]-2,1,3-oxadiazoldiole-5,7 complex, rhodium trichloride, complexing, synthesis, water -acetone medium, fragmentation
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