It is shown that injection of silver nanoparticles (NPs) into large-tonnage polymers, such as polystyrene (PS) and styrene copolymer with acrylonitrile (SAN), imparts fungicide properties to them. For the purpose of further forecasting, the process of microscopic fungi and bacteria growth in the presence of different silver NP concentrations has been described quantitatively. It is shown that addition of silver NPs significantly suppresses growth of Aspergillus niger and Penicillium chrysogenum microscopic fungi both at the initial, and stationary stages of their growth. Inhibition of bacterial growth manifests itself in increased induction period (the lag-phase).
nanotechnology, biotechnology, fungicides, biocides, silver nanoparticles, нанотехнология, фунгициды, биоциды, полистирол, наноструктурные частицы серебра
1. G. Zhao, Jr. S.E. Stevens, Biometals, 11, 27-32 (1998);
2. F.Furno, K.S. Morley, B.Wong, B.L. Sharp, P.L. Arnold, S.M. Howdle et al., J. Antimicrob. Chemother., 54, 1019-1024 (2004);
3. Jun Sung Kim, Eunye Kuk, KyeongNamYu, Jong Lee, So Hyun Kim, Young Kyung Park, Yong Kyung Park, Cheol-Yong Hwang, Yong-Kwon Kim, Yoon-Sik Lee, Dae Hong Jeong, Myung-Haing Cho, Nanomedicine: Nanotechnology, Biology and Medicine, 3, 1, 95-101 (2007);
4. S. Aymonier, U. Schlotterbeck, L. Antonietti, Ph. Zacharias, R. Thomann, J. C. Tiller, S. Mecking, Chem. Commun., 8, 24, 3018-3019 (2002);
5. E.V. Anishchenko, G.V. Lyamina, N. M. Korshikova, G.M. Mokrousov, Izv. TPU, 309,1, (2006);
6. T. Hamouda, A. Myc, B. Danovan, A. Shih, J. D. Reuter, Jr. J. R. Baker, Microbiol. Res. 156, 1-7 (2000);
7. P. Dibrov, J. Dzioba, K.K. Gosink, C.C. Hase, Antimicrob. Agents Chemother, 46, 2668-2670 (2002);
8. I. Dragieva, S. Stoeva, P. Stoimenov, E. Pavlikianov, K. Klabunde, Nanostruct. Mater. , 12, 267-270 (1999);
9. I. Sondi, B. Salopek-Sondi, J. Colloid. Interface. Sci., 275, 177-182 (2004);
10. N.A. Amro, L.P. Kotra, K. Wadu-Mesthrige, A. Bulychev, S. Mobashery, G. Liu, Langmuir, 16, 2789-2796 (2000);
11. M. Danilczuk, A. Lund, J. Saldo, H. Yamada, J. Michalik, Spectrochimaca Acta Part A, 63, 189-191 (2006);
12. P.K. Stoimenov, R.L. Klinger, G.L. Marchin, K.J. Klabunde, Langmuir, 18, 6679 (2002);
13. Q.L. Feng, J. Wu, G. Q. Chen, F. Z. Cui, T. M. Kim, J.O. Kim, J. Biomed. Mater. Res., 52, 662 (2000);
14. J. A. Spadaro, t. J. Berger, S. D. Barranco, S. E. Chapin, R. O. Becker, Microb. Agents Chemother., 6, 637 (1974);
15. O.T. Kasaikina, Z.S. Kartasheva, L.M. Pisarenko, Zh. Obshch. Khim., 78, 8, 1298-1309 (2008);
16. O.T. Kasaikina, A.A. Golyavin, D.A. Krugovov, Z.S. Kartasheva, L.M. Pisarenko, Vestn. MGU, Ser. Khim., p. 246-250 (2010);
17. E.A. Mengele, Z.S. Kartasheva, I.G. Plashchina, O.T. Kasaikina, Koll. Zh., 70, 6, 805-811 (2008);
18. O.T. Kasaikina, V.D. Kortenska, Z.S. Kartasheva et. al., Colloid and Surface, A, Physicochemistry and Engineering, 149, 29 (1999);
19. A.A. Korenevsky, V.V. Sorokin, G.I. Karavaiko, Mikrobiologia, 62, 6, 1085-1092 (1993);
20. Woo Kyung Jung, Hye Cheong Koo, Ki Woo Kim, Sook Shin, So Hyun Kim, and Yong Ho Park, Appl. and Environmental Microbiology, 74, 7, 2171-2178 (2008);
21. Zhang S. And Crow S.A. Jr. Applied and Environmental Microbiology, 67, 9, 4030-4035(2001).
22. E. M. Egorova, A.A. Revina, T.N. Rostovshchikova, O.I. Kiseleva, Vestn. MGU, Ser. 2, Khimia, 42, 332-338.(2001);
23. A.P. Kumar, D. Depan, N.S. Tomer, R.P. Singh, Progress in polymer science, 34, 6, 479-515 (2009);
24. M.M. Reddy, M. Deghton, R.K. Gupta, S.N. Bhat-acharya, R. Parthasaraty J. of Appl. Polym. Sci., 111, 3, 1426-1432. (2009);
25. K. Z. Gumargalieva, I. G. Kalinina, S. A. Semenov, G. E. Zaikov, L. A. Zimina, M. I. Artsis, RFP intern., 6, 2, 114-120(2011);
26. I.G. Kalinina, K.Z. Gumargalieva, O.N. Kuznetsova, G.E. Zaikov, Vestn. Kazakhsk. Tekhnol. Univ., 15, 12, 115-119 (2012);
27. Kalinina I.G., Belov G.P., Gumargalieva K.Z., Petronyuk Yu.S., Semenov S.A. Khim. Fizika, 30, 2, 70-79 ( 2011);
28. S.N. Mironova, A.A. Malama, T.V. Filimonova, Yu.V. Moiseev, K.Z. Gumargalieva, S.A. Semenov, V.P. Mironov, L.E. Grushevich, Dokl. AN BSSR, 34, 6, 228-560 (1985);
29. K.Z. Gumargalieva, I.G. Kalinina, Polimernye Materialy, 7-8, 58-62 (2010);
30. K.Z. Gumargalieva, I.G. Kalinina, Polimernye Materialy, 10, 18-24 (2010);
31. GOST 9.048-89. ESZKS Technical Products. Methods for Laboratory Tests for Resistance to the Effect of Mold Fungi;
32. GOST 9.049-91. Polymeric Materials and Their Components. Methods for Laboratory Tests for Resistance to the Effect of Mold Fungi (Method 3);
33. N.M. Emanuel, Kinetics of Experimental Tumour Processes. Nauka, Moscow, 1977. 354 p.;
34. K.Z. Gumargalieva, I.G. Kalinina, S.N. Mironova, S.A. Semenov, Mikrobiologia, 57, 5, 879-882 (1988);
35. K. Z. Gumargalieva, G. E. Zaikov, Biodegradation and Biodeterioration of Polymers: Kinetical Aspects. Nova Science Publishers. Inc. Commack, New York, 1998. 409 P;
36. K. Z. Gumargalieva, I. G.Kalinina, G.E. Zaikov, S. A. Semenov, A. I. Ryzhkov, Chem. Phys. Reports, 15, 10, 1463 -1476( 1996)
